PKt8 'QD9D9refs.MYD?,Tang, Q. Shi, S. Q. Huang, H. T. Zhou, L. M.2004Fabrication of highly oriented microstructures and nanostructures of ferroelectric P(VDF-TrFE) copolymer via dip-pen nanolithography21-29!Superlattices and Microstructures361-3Jul-Sep>Microstructures and nanostructures of ferroelectric copolymer poly(vinylidene fluoride-trifluorethylene) [P(VDF-TrFE)] are fabricated on gold via dip-pen nanolithography (DPN). The thickness of the patterns is about I nm after a critical concentration, regardless of the pattern scale. The polymer molecules are well orientated according to an all-trans conformation and have ferroelectric properties on the gold surface through electrostatic interaction, rather than the formation of chemical bonds. Increasing temperature has a positive effect on the growth rate of the P(VDF-TrFE). The electrostatic interaction between the P(VDF-TrFE) and the gold substrate and the intramolecular interaction of polymer molecules play important roles in the growth rate of the P(VDF-TrFE) patterns. (C) 2004 Elsevier Ltd. All rights reserved.://000225425100003ISI:000225425100003 file://S:\SALES\_IMPORTANT_STUFF_HERE\Bibliography_Key_Papers\all publications DPN as of 101006 Copy.Data\PDF\2004 Superlattices & Microstructures Tang Fabricatio-0135437391\2004 Superlattices & Microstructures Tang Fabrication of highly oriented microstructures.pdf?/Su, M. Aslam, M. Fu, L. Wu, N. Q. Dravid, V. P.2004ODip-pen nanopatterning of photosensitive conducting polymer using a monomer ink 4200-4202Applied Physics Letters8421May 24Controlled patterning of conducting polymers at a micro- or nanoscale is the first step towards the fabrication of miniaturized functional devices. Here, we introduce an approach for the nanopatterning of conducting polymers using an improved monomer "ink" in dip-pen nanolithography (DPN). The nominal monomer "ink" is converted, in situ, to its conducting solid-state polymeric form after patterned. Proof-of-concept experiments have been performed with acid-promoted polymerization of pyrrole in a less reactive environment (tetrahydrofuran). The ratios of reactants are optimized to give an appropriate rate to match the operation of DPN. A similar synthesis process for the same polymer in its bulk form shows a high conductance and crystalline structure. The miniaturized conducting polymer sensors with light detection ability are fabricated by DPN using the improved ink formula, and exhibit excellent response, recovery, and sensitivity parameters. (C) 2004 American Institute of Physics.://000221404700021ISI:000221404700021 file://S:\SALES\_IMPORTANT_STUFF_HERE\Bibliography_Key_Papers\all publications DPN as of 101006 Copy.Data\PDF\2004 Applied Physics Letters Su DP nanopatterning of p-1022295630\2004 Applied Physics Letters Su DP nanopatterning of photosensitive conducting polymer.pdf ?Lim, J. H. Mirkin, C. A.2002GElectrostatically driven dip-pen nanolithography of conducting polymers1474-+Advanced Materials1420Oct 16Nanoscale conducting polymer patterns have been fabricated on modified semiconductor substrates using dip-pen nanolithography (DPN). Electrostatic interactions between water-soluble ink materials and charged substrates are the driving force for the generation of stable DPN patterns. The conducting polymers have been characterized by lateral force microscopy (see Figure) and electrochemical methods.://000179034200008ISI:0001790342000081002908001Slides.pptinternal-pdf://2002 AdvMats Lim Electrostatically driven DPN Nanolith-1882359593/2002 AdvMats Lim Electrostatically driven DPN Nanolith.pdfG}?NVega, R. A. Shen, C. K. F. Maspoch, D. Robach, J. G. Lamb tan.ac.kriinternal-pdf://2006_ JPCB_Growth Dynamics of SAM_Ahn-3905701633/2006_ JPCB_Growth Dynamics of SAM_Ahn.pdf s f.ac.ukiinternal-pdf://2006_NL_Fabrication of Biological_Sun-3704538881/2006_NL_Fabrication of Biological_Sun.pdf qic.dtu.dkeinternal-pdf://2005_Fabrication_Biomolecular_Dufva-0913139210/2005_Fabrication_Biomolecular_Dufva.pdf 8Lstrate Interactions59-74 Annals of Biomedical Engineering341internal-pdf://2006_ABE_Sniadecki_Nanotech for cell substrate interactions- 14853 USA.internal-pdf://2005 Biomacromolecules Senaratne Self-assembled monolayers & polymer brushes-4238888971/2005 Biomacromolecules Senaratne Self-assembled monolayers & polymer brushes.pdf hydrogen-passivated silicon with conductive-diamond-coated probes 2053-2056Small312Dec://000251697100012 1613-6810ISI:000251697100012 9ive_Kidambi-3868341765/2008_Tunable resistive_Kidambi.pdf %o,rnal-pdf://2007_Power of the pen_Mirk0F~? Striolo, A.2006GAdsorption of model surfactantlike copolymers on nanopatterned surfacesJournal of Chemical Physics1259SELF-ASSEMBLED MONOLAYERS; TRANSFER RADICAL POLYMERIZATION; DIP-PEN NANOLITHOGRAPHY; POLY(ETHYLENE OXIDE); MOLECULAR-DYNAMICS; GRADUAL VARIATION; NANOMETER-SCALE; BRUSHES; GOLD; PARTICLESArticleSepThe adsorption of polymers, copolymers, surfactants, and biopolymers is often used to engineer surfaces. Towards improving our understanding of polymer adsorption we report simulation results for the adsorption of model copolymers, resembling surfactants, on nanoscale patterned hydrophobic surfaces at infinitely dilute concentrations. The surfactants are composed by a hydrophobic tail and a hydrophilic head. Surfactant adsorption on the hydrophobic surface occurs in the tail-down configuration in which the tail segments are in contact with the surface. We investigate how the presence of a solid hard mask, used to create the nanoscale pattern on the underlying hydrophobic surface, affects the surfactant adsorption. We find that surfactant adsorption on the underlying hydrophobic surface is prevented when the characteristic dimensions of the solid hard mask are less than twice the radius of gyration. We also show that details about mask-surfactant head effective interactions have the potential to alter the characteristics of adsorption. When the mask repels the head segments, the surfactants hardly adsorb on the underlying hydrophobic surface. When the mask strongly attracts the surfactant heads, the surfactants may preferentially adsorb on the mask rather than on the underlying hydrophobic surface. Under these latter circumstances the adsorbed surfactants in some cases assume a head-down configuration in which the head segments are in contact with the mask and the tail segments extend towards the bulk solution. We explain our results in terms of enthalpy and entropy of adsorption and discuss practical implications. (c) 2006 American Institute of Physics.://000240351500045 Times Cited: 0 Cited References: ABBOTT NL, 1992, SCIENCE, V257, P1380 AUGUSTE DT, 2003, BBA-BIOMEMBRANES, V1616, P184 BERGGREN KK, 1995, SCIENCE, V269, P1255 BOYES SG, 2002, MACROMOLECULES, V35, P4960 BRANTLEY EL, 2004, MACROMOLECULES, V37, P1476 CEPAK VM, 1999, CHEM MATER, V11, P1363 CHABINYC ML, 2002, APPL PHYS LETT, V81, P4260 CHAKRABORTY AK, 1991, MACROMOLECULES, V24, P5226 CHAKRABORTY AK, 1996, MRS BULL, V21, P28 CHAKRABORTY AK, 1998, J CHEM PHYS, V108, P1676 CHEN XY, 2004, LANGMUIR, V20, P587 CHUN KY, 2003, J CHEM PHYS, V118, P3252 DAUNTENHAHN J, 1994, MACROMOLECULES, V27, P5399 DENIS FA, 2002, LANGMUIR, V18, P819 DOUGLAS JF, 1989, MACROMOLECULES, V22, P3707 FAN FQ, 2004, LANGMUIR, V20, P3062 GAREL T, 1990, J PHYS A-MATH GEN, V23, L621 GENZER J, 2001, J CHEM PHYS, V115, P4873 GRANVILLE AM, 2004, MACROMOLECULES, V37, P2790 GUTOWSKI WS, 2003, J ADHESION, V79, P445 HANSEN JP, 1986, THEORY SIMPLE LIQUID HARWELL JH, 1993, ADSORPTION MIXED SUR HESTER JF, 2002, J MEMBRANE SCI, V202, P119 HIGGS PG, 1991, J CHEM PHYS, V95, P4506 HUANG YW, 2001, MACROMOLECULES, V34, P3757 HUANG YW, 2002, LANGMUIR, V18, P2280 HUANG YW, 2003, LANGMUIR, V19, P2175 HUANG YW, 2004, J CHEM PHYS, V121, P2264 HUSEMANN M, 1998, ANGEW CHEM INT EDIT, V37, P550 JENNINGS GK, 2003, J AM CHEM SOC, V125, P2950 JORDAN R, 2001, MACROMOLECULES, V34, P1606 KUMAR A, 1992, J AM CHEM SOC, V114, P9188 LAHANN J, 2003, SCIENCE, V299, P371 LEMEINS JF, 2003, COLLOID POLYM SCI, V281, P283 LIN GY, 1994, LANGMUIR, V10, P367 LIU H, 1999, POLYMER, V40, P7285 LIU XG, 2003, ANGEW CHEM INT EDIT, V42, P4785 LU Y, 2005, NANO LETT, V5, P5 MARQUEZ M, IN PRESS LANGMUIR MULLER WT, 1995, SCIENCE, V268, P272 NORDE I, 1995, SURFACE INTERFACIAL PALLANDRE A, 2005, J AM CHEM SOC, V127, P4320 PINER RD, 1999, SCIENCE, V283, P661 QIN SH, 2004, J AM CHEM SOC, V126, P170 SCHMELMER U, 2003, ANGEW CHEM INT EDIT, V42, P559 STRIOLO A, 2001, FLUID PHASE EQUILIBR, V183, P341 STRIOLO A, 2001, J CHEM PHYS, V114, P8565 STRIOLO A, 2004, MOL SIMULAT, V30, P437 STRIOLO A, 2005, J CHEM PHYS, V123 SUN KY, 2004, BIOMATERIALS, V25, P557 SUN TL, 2004, ANGEW CHEM INT EDIT, V43, P357 SUNG WY, 2005, PHYS REV E 1, V71 TARLOV MJ, 1993, J AM CHEM SOC, V115, P5305 TOMLINSON MR, 2003, MACROMOLECULES, V36, P3449 TUMMALA NR, UNPUB WANG JY, 1994, LANGMUIR, V10, P626 WEI X, 2003, J COLLOID INTERF SCI, V264, P296 WILSON DL, 2001, P NATL ACAD SCI USA, V98, P13660 WU T, 2003, MACROMOLECULES, V36, P2448 XIA TK, 1993, SCIENCE, V261, P1310 XIA YN, 1995, J AM CHEM SOC, V117, P3274 XU S, 1999, LANGMUIR, V15, P7244 ZAJAC R, 1997, J CHEM PHYS, V107, P8637 ZHOU F, 2003, ADV FUNCT MATER, V13, P938ISI:000240351500045Univ Oklahoma, Sch Chem Biol & Mat Engn, Sarkeys Energy Ctr T235, Norman, OK 73019 USA. Striolo, A, Univ Oklahoma, Sch Chem Biol & Mat Engn, Sarkeys Energy Ctr T235, Norman, OK 73019 USA. astriolo@ou.edu094709 Artn 094709internal-pdf://2006 JoChemPhys Striolo Adsorption of model surfactantlike-1686979087/2006 JoChemPhys Striolo Adsorption of model surfactantlike.pdf notechnology for Cell-Sub ~?]Slocik, J. M. Beckel, E. R. Jiang, H. Enlow, J. O. Zabinski, J. S. Bunning, T. J. Naik, R. R.2006Site-speciric patterning of biomolecules and quantum dots on functionalized surfaces generated by plasma-enhanced chemical vapor deposition2095-+Advanced Materials1816SELF-ASSEMBLED MONOLAYERS; DIP-PEN NANOLITHOGRAPHY; AQUEOUS-SOLUTION; THIN-FILMS; PROTEIN; NANOPARTICLES; SILICON; DNA; NANOSTRUCTURES; LITHOGRAPHYArticleAugPlasma-enhanced chemical vapor patterned surfaces are used for site-specific attachment of biomolecules and semiconductor quantum dots (QDs; see figure). The fabrication of surfaces with multiple functional building blocks can be used in a single step to create complex multifunctional patterned substrates incorporating self-assembled monolayers (SAMs) and thiol-functionalized quantum dots for a variety of applications.://000240408600002 Times Cited: 0 Cited References: AGARWAL G, 2003, J AM CHEM SOC, V125, P580 AGARWAL G, 2003, J AM CHEM SOC, V125, P7408 AHN SJ, 2005, J AM CERAM SOC, V88, P1171 BERGMAN AA, 1998, LANGMUIR, V14, P6785 BHATNAGAR P, 2006, ADV MATER, V18, P315 CALDERON JG, 1998, J BIOMED MATER RES, V42, P2541 CARUSO F, 2000, LANGMUIR, V16, P9595 DAW R, 1998, BIOMATERIALS, V19, P1717 DYAL A, 2003, J AM CHEM SOC, V34, P1684 FAVIA P, 2003, SURF COAT TECH, V169, P707 FUNG YS, 2001, ANAL CHEM, V73, P5302 GRANT JT, 2005, VACUUM, V80, P12 HAES AJ, 2002, J AM CHEM SOC, V124, P10596 HOLDCROFT S, 2001, ADV MATER, V13, P1753 INEROWICZ HD, 2002, LANGMUIR, V18, P5263 JIANG H, 2004, CHEM MATER, V16, P1292 JUNG D, 2006, SURF COAT TECH, V200, P2886 KAHANA J, 1996, CURRENT PROTOCOLS MO KANE RS, 1999, BIOMATERIALS, V20, P2363 LEE KB, 2003, J AM CHEM SOC, V125, P5588 LEE SH, 2005, SENSOR ACTUAT B-CHEM, V110, P164 LEI CH, 2002, J AM CHEM SOC, V124, P11242 LENIGK R, 2001, LANGMUIR, V17, P2497 LIU MZ, 2002, NANO LETTERS, V2, P863 LOOS K, 2005, LANGMUIR, V21, P5237 MASUDA Y, 2003, CHEM MATER, V15, P2469 NILSSON S, 1995, ANAL CHEM, V67, P3051 SHAPLEY JDL, 2001, THIN SOLID FILMS, V388, P134 SMITH K, 2002, J AM CHEM SOC, V124, P4247 VEISEH M, 2002, LANGMUIR, V18, P6671 VOGT AK, 2003, BIOTECHNOL PROGR, V19, P1562 WADUMESTHRIGE K, 1999, LANGMUIR, V15, P8580 WALBA DM, 2004, LIQ CRYST, V31, P481 WANG C, 2005, ADV MATER, V17, P150 XU H, 2006, J AM CHEM SOC, V128, P3162 ZELIKIN AN, 2006, BIOMACROMOLECULES, V7, P27 ZHANG G, 2005, SMALL, V8, P833 ZHENG HP, 2004, LANGMUIR, V20, P7215ISI:000240408600002USAF, Res Lab, Mat & Mfg Directorate, Dayton, OH 45433 USA. Anteon Corp, Dayton, OH 45431 USA. Naik, RR, USAF, Res Lab, Mat & Mfg Directorate, Dayton, OH 45433 USA. rajesh.naik@wpafb.af.milinternal-pdf://2006 Advanced Materials Slocik Site-specific pat-1418782991/2006 Advanced Materials Slocik Site-specific patterning of biomolecules & quantum dots.pdfCK(?1Sniadecki, N.J. Desai, R.A. Ruiz, S.A. Chen, C.S.2006.Na/8~; HChandekar, A. Sengupta, S. K. Barry, C. M. F. Mead, J. L. Whitten, J. E.2006WTemplate-directed adsorption of block copolymers on alkanethiol-patterned gold surfaces 8071-8077Langmuir2219SELF-ASSEMBLED MONOLAYERS; ATOMIC-FORCE MICROSCOPE; NANOIMPRINT LITHOGRAPHY; POLYMERS; FILMS; WETTABILITY; ADHESION; DENSITY; DOMAINS; MOLDArticleSepFunctionalized alkanethiols have been self-assembled on gold to modify the wetting properties of the surface and promote or hinder the adsorption of block copolymers containing both hydrophobic and hydrophilic blocks. X-ray photoelectron spectroscopy (XPS) studies of spin-coated polyethylene-block-poly(ethylene oxide) (PE-b-PEO) copolymers on 16-mercaptohexadecanoic acid (MHDA)-, octadecanethiol (ODT)-, and 1H,1H,2H,2H-perfluorodecanethiol (PFDT)-covered surfaces have been performed. In the case of an 80 wt% PEO block copolymer, spin-coating on a gold surface precovered with MHDA results in a polymer film thick enough to completely attenuate Au 4f photoelectrons; spin-coating on the more hydrophobic ODT and PFDT monolayers leads to significantly thinner polymer films and incomplete attenuation of the gold photoelectrons. The opposite results are observed when a 20 wt % PEO block copolymer is used. Angle-resolved XPS studies of the 80 wt % PEO block copolymer spin-coated onto an MHDA-covered surface indicate that the PE blocks of the polymer segregate to the near-surface region, oriented away from the hydrophilic carboxylic acid tails of the monolayers; the surface concentration of PE is further enhanced by annealing at 90 degrees C. Microcontact printing and dip-pen nanolithography have been used to pattern gold surfaces with MHDA, and the surfaces have been backfilled with ODT or PFDT, such that the unpatterned regions of the surface are covered with hydrophobic monolayers. In the case of backfilling with PFDT, spin-coating the 80 wt% PEO copolymer onto these patterned surfaces and subsequent annealing results in the block copolymer preferentially adsorbing on the MHDA-covered regions and forming well-defined patterns that mimic the MHDA pattern, as determined by scanning electron microscopy and atomic force microscopy. Significantly worse patterning, characterized by micron-sized polymer droplets, results when the surface is backfilled with ODT instead of PFDT. Using PFDT and MHDA, polymer features having widths as small as 500 nm have been formed. These studies demonstrate a novel method to pattern block copolymers with nanoscale resolution.://000240250600021 Times Cited: 0 Cited References: AGUILAR CA, 2005, BIOMATERIALS, V26, P7642 BAIN CD, 1989, J AM CHEM SOC, V111, P321 BEHL M, 2002, ADV MATER, V14, P588 CHILDS WR, 2002, J AM CHEM SOC, V124, P13583 COLORADO R, 2000, J PHYS ORG CHEM, V13, P796 DECKER EL, 1997, LANGMUIR, V13, P6321 EDWARDS EW, 2004, ADV MATER, V16, P1315 EDWARDS EW, 2005, J POLYM SCI POL PHYS, V43, P3444 FUKUSHIMA H, 2000, J PHYS CHEM B, V104, P7417 GARBASSI F, 1994, POLYM SURFACES, P327 HAWKER CJ, 2005, MRS BULL, V30, P952 HOUSTON JE, 2005, LANGMUIR, V21, P3926 JEGADESAN S, 2006, LANGMUIR, V22, P780 KIM YS, 2005, CHEM MATER, V17, P5867 KISS E, 1996, LANGMUIR, V12, P1651 LAIBINIS PE, 1991, J AM CHEM SOC, V113, P7152 LYUKSYUTOV SF, 2003, APPL PHYS LETT, V83, P4405 MAMIN HJ, 1992, APPL PHYS LETT, V61, P1003 MAURY P, 2005, ADV MATER, V17, P2718 MCCLELLAND GM, 2002, APPL PHYS LETT, V81, P1483 MEYER E, 2000, MACROMOL MATER ENG, V276, P44 MIURA YF, 1998, LANGMUIR, V14, P5821 PARK JS, 2005, LANGMUIR, V21, P2902 SEAH MP, 1979, SURFACE INTERFACE AN, V1, P2 STOYKOVICH MP, 2005, SCIENCE, V308, P1442 SUNDRANI D, 2004, NANO LETT, V4, P273 TOKUHISA H, 2004, LANGMUIR, V20, P1436 VANDEGRAMPEL RD, 2004, LANGMUIR, V20, P145 WAGNER AJ, 2002, LANGMUIR, V18, P1542 WANG H, 2005, LANGMUIR, V21, P2633 WANG MS, 2004, LANGMUIR, V20, P7753 WANG Y, 2005, J PHYS CHEM B, V109, P12376 WATTS JF, 2003, INTRO SURFACE ANAL X, P80 WILBUR JL, 1994, ADV MATER, V6, P600 XIA YN, 1997, ADV MATER, V9, P147 XIANG HQ, 2004, MACROMOLECULES, V37, P5358 YIN YD, 2003, J AM CHEM SOC, V125, P2048ISI:000240250600021Univ Massachusetts, Dept Chem, Lowell, MA 01854 USA. Univ Massachusetts, Ctr High Rate Nanomfg, Lowell, MA 01854 USA. Univ Massachusetts, Dept Plast Engn, Lowell, MA 01854 USA. Whitten, JE, Univ Massachusetts, Dept Chem, 1 Univ Ave, Lowell, MA 01854 USA. James_Whitten@uml.edu2625313603d Block Copolymer.ppt <~? 8Gao, H. Gosvami, N. N. Deng, J. Tan, L. S. Sander, M. S.2006UTemplate-assisted patterning of nanoscale self-assembled monolayer arrays on surfaces 8078-8082Langmuir2219DIP-PEN NANOLITHOGRAPHY; ANODIC ALUMINA FILMS; SOFT LITHOGRAPHY; ALIGNED ARRAYS; FABRICATION; OXIDE; NANOFABRICATION; NANOSTRUCTURES; NANOTUBES; SILVERArticleSepWe report a general, simple, and inexpensive approach to pattern features of self-assembled monolayers (SAMs) on silicon and gold surfaces using porous anodic alumina films as templates. The SAM patterns, with feature sizes down to 30 nm and densities higher than 10(10)/cm(2), can be prepared over large areas (> 5 cm(2)). The feature dimensions can be tuned by controlling the alumina template structure. These SAM patterns have been successfully used as resists for fabricating gold and silicon nanoparticle arrays on substrates by wet-chemical etching. In addition, we show that arrays of gold features can be patterned with 10-nm gaps between the dots.://000240250600022 Times Cited: 0 Cited References: AIZENBERG J, 2003, SCIENCE, V299, P1205 CAI AL, 2002, NANOTECHNOLOGY, V13, P627 CHENG GS, 2002, ADV MATER, V14, P1567 CHU SZ, 2002, ADV MATER, V14, P1752 COJOCARU CS, 2005, NANO LETT, V5, P675 DANIEL MC, 2004, CHEM REV, V104, P293 FELIDJ N, 2002, PHYS REV B, P65 FINNIE KR, 2001, LANGMUIR, V17, P1250 GAO H, 2003, J APPL PHYS, V93, P5602 GATES BD, 2005, CHEM REV, V105, P1171 GEISSLER M, 2004, ADV MATER, V16, P1249 GOLZHAUSER A, 2001, ADV MATER, V13, P806 HE L, 2000, J AM CHEM SOC, V122, P9071 KOVTYUKHOVA NI, 2003, ADV MATER, V15, P780 LEE KB, 2002, SCIENCE, V295, P1702 LEI Y, 2005, J AM CHEM SOC, V127, P1487 LI AP, 1998, J APPL PHYS, V84, P6023 LI FY, 1998, CHEM MATER, V10, P2470 LIU GY, 2000, ACCOUNTS CHEM RES, V33, P457 LOVE JC, 2005, CHEM REV, V105, P1103 LU N, 2002, ADV MATER, V14, P1812 MAOZ R, 2000, ADV MATER, V12, P424 MARTIN CR, 1994, SCIENCE, V266, P1961 MASUDA H, 1995, SCIENCE, V268, P1466 MASUDA H, 2001, ADV MATER, V13, P247 MAURY P, 2005, ADV FUNCT MATER, V15, P451 MCLELLAN JM, 2004, J AM CHEM SOC, V126, P10830 ODOM TW, 2002, LANGMUIR, V18, P5314 PALLANDRE A, 2004, NANO LETT, V4, P365 PINER RD, 1999, SCIENCE, V283, P661 PORTER LA, 2002, NANO LETT, V2, P1369 PRIME KL, 1991, SCIENCE, V252, P1164 RABIN O, 2003, ADV FUNCT MATER, V13, P631 SALAITA K, 2005, SMALL, V1, P940 SANDER MS, 2003, ADV FUNCT MATER, V13, P393 SANDER MS, 2004, ADV MATER, V16, P2052 SANDER MS, 2005, J AM CHEM SOC, V127, P12158 SCHMID H, 2000, MACROMOLECULES, V33, P3042 SMITH RK, 2004, PROG SURF SCI, V75, P1 STAMOU D, 2004, LANGMUIR, V20, P3495 SUN SQ, 2002, NANO LETT, V2, P1223 TARLOV MJ, 1993, J AM CHEM SOC, V115, P5305 TIAN ML, 2005, NANO LETT, V5, P697 WANG H, 2005, J AM CHEM SOC, V127, P14992 WEINBERGER DA, 2000, ADV MATER, V12, P1600 ZHANG H, 2003, NANO LETT, V3, P43ISI:000240250600022Inst Mat Res & Engn, Singapore 117602, Singapore. Gao, H, Inst Mat Res & Engn, Singapore 117602, Singapore. h-gao@imre.a-star.edu.sg{internal-pdf://2006_Langmuir_Template-assisted patterning_Gao-1489457679/2006_Langmuir_Template-assisted patterning_Gao.pdfPc26441259\2006 Langmuir Gao Template -assisted patterning.pdf ~? )Downard, A. J. Tan, E. S. Q. Yu, S. S. C.2006<Controlled assembly of gold nanoparticles on carbon surfaces 1283-1288New Journal of Chemistry309DIP-PEN NANOLITHOGRAPHY; GLASSY-CARBON; ELECTROCHEMICAL OXIDATION; MERCURY-ELECTRODES; PROTEIN ADSORPTION; SILICON SURFACES; FIBER SURFACES; MONOLAYERS; FILMS; IMMOBILIZATIONArticleCitrate-capped gold nanoparticles are electrostatically assembled on amine films attached to carbon surfaces. Primary amines are covalently grafted to carbon surfaces by an electrochemically-assisted method which gives easy control of the number of amine functionalities on the surface, and hence the density of the nanoparticle assembly. Further control of nanoparticle assemblies can be gained by choice of the amine modifier, and by adjusting the nanoparticle concentration, assembly time and pH of the nanoparticle solution. This simple and versatile approach for preparation of tethered nanoparticle assemblies should be compatible with any conducting carbon substrate, giving new materials for applications ranging from catalysis to sensing.://000240109100005 bTimes Cited: 0 Cited References: ADENIER A, 2004, LANGMUIR, V20, P8243 ANTONIADOU S, 1992, J APPL ELECTROCHEM, V22, P1060 BARBIER B, 1990, J ELECTROCHEM SOC, V137, P1757 BECKA AM, 1993, J PHYS CHEM-US, V97, P6233 BROOKSBY PA, 2004, LANGMUIR, V20, P5038 BROOKSBY PA, 2005, LANGMUIR, V21, P11304 BRUST M, 2002, COLLOID SURFACE A, V202, P175 BUTTRY DA, 1999, CARBON, V37, P1929 CHAN EWL, 2002, LANGMUIR, V18, P311 COULON E, 2001, LANGMUIR, V17, P7102 COULON E, 2002, J ORG CHEM, V67, P8513 DANIEL MC, 2004, CHEM REV, V104, P293 DEINHAMMER RS, 1994, LANGMUIR, V10, P1306 DEMERS LM, 2001, ANGEW CHEM INT EDIT, V40, P3071 DEMERS LM, 2002, SCIENCE, V296, P1836 DOWNARD AJ, 1999, ELECTROANAL, V11, P418 DOWNARD AJ, 2000, ELECTROANAL, V12, P1085 DOWNARD AJ, 2005, AUST J CHEM, V58, P275 FRENCH M, 1998, LANGMUIR, V14, P2129 GENESTE F, 2005, NEW J CHEM, V29, P269 GRABAR KC, 1995, ANAL CHEM, V67, P735 GRABAR KC, 1996, J AM CHEM SOC, V118, P1148 HAN XJ, 2003, ANAL CHEM, V75, P6566 HARNISCH JA, 2001, J AM CHEM SOC, V123, P5829 HAYES MA, 1999, ANAL CHEM, V71, P1720 HOEKSTRA KJ, 1996, CHEM MATER, V8, P1865 HUANG XH, 2000, SURF SCI, V459, P183 KOSTECKI R, 2001, THIN SOLID FILMS, V396, P36 LIU JY, 2000, ELECTROCHEM COMMUN, V2, P707 LIU ST, 2002, PHYS CHEM CHEM PHYS, V4, P6059 LIU ST, 2004, NANO LETT, V4, P845 MAYA L, 2002, LANGMUIR, V18, P2392 MENDES PM, 2004, LANGMUIR, V20, P3766 RANGANATHAN S, 2001, ANAL CHEM, V73, P893 SAUNDERS KH, 1985, AROMATIC DIAZO COMPO SEITZ O, 2003, COLLOID SURFACE A, V218, P225 SLOWINSKI K, 1997, J AM CHEM SOC, V119, P11910 SLOWINSKI K, 1999, J PHYS CHEM B, V103, P8544 TANAKA H, 1997, J ELECTROANAL CHEM, V437, P29 TIEN J, 1997, LANGMUIR, V13, P5349 TOGNARELLI DJ, 2005, LANGMUIR, V21, P11119 WANG J, 1998, THIN SOLID FILMS, V327, P591 YAMANOI Y, 2004, LANGMUIR, V20, P1054 ZANELLA R, 2005, J PHYS CHEM B, V109, P16290 ZHANG H, 2002, ADV MATER, V14, P1472 ZHU T, 1999, LANGMUIR, V15, P5197ISI:000240109100005Univ Canterbury, Dept Chem, MacDiarmid Inst Adv Mat & Nanotechnol, Christchurch 1, New Zealand. Downard, AJ, Univ Canterbury, Dept Chem, MacDiarmid Inst Adv Mat & Nanotechnol, Private Bag 4800, Christchurch 1, New Zealand. alison.downard@canterbury.ac.nzinternal-pdf://2006 New Jo of Chem Downard Controlled Assembly of A-1774937615/2006 New Jo of Chem Downard Controlled Assembly of AU nanoparticles on carbon surf.pdf<Ttrolled assembly of au nanoparticles.pdf~? Zhou, D. J. Kang, D. J.2005iCreating functional nanostructured materials at the crossroad of physics, chemistry and materials Science440-468'International Journal of Nanotechnology24Bnanostructure; self-assembled monolayer; layer-by-layer assembly; soft lithography; nanopipet delivery RESONANCE ENERGY-TRANSFER; DIP-PEN NANOLITHOGRAPHY; SELF-ASSEMBLED MONOLAYERS; ATOMIC-FORCE MICROSCOPY; QUANTUM DOTS; HORSERADISH-PEROXIDASE; PROTEIN NANOSTRUCTURES; CONTROLLED DEPOSITION; GOLD NANOPARTICLES; THIN-FILMSReviewControlled assembly and manipulation of three-dimensional (3D) nanostructures with well-defined shapes, profiles and functionalities present a significant challenge to nanotechnology. In this paper we summarise our recent efforts in an attempt to solve this problem by developing a highly selective surface-templated layer-by-layer assembly, where top-down approaches such as soft lithography, focused-ion beam lithography and voltage-controlled nanopipet delivery are combined with bottom-up techniques like self-assembly, molecular recognition and layer-by-layer assembly to controllably deposit and grow 2D to 3D micro/nanostructures with functional materials. This opens up wide applications in highly sensitive biosensors, miniaturised assays, and functional 3D nano-assemblies and devices.://000239797900007 0Times Cited: 0 Cited References: AGARWAL G, 2003, J AM CHEM SOC, V125, P7408 AI H, 2002, BIOMACROMOLECULES, V3, P560 ALBERTI P, 2003, P NATL ACAD SCI USA, V100, P1569 ALIVISATOS AP, 1996, SCIENCE, V271, P933 ALIVISATOS AP, 2004, NAT BIOTECHNOL, V22, P47 BARTLETT PN, 1999, J ELECTROCHEM SOC, V146, P1088 BORNSCHEUER UT, 2003, ANGEW CHEM INT EDIT, V42, P3336 BRUCKBAUER A, 2002, J AM CHEM SOC, V124, P8810 BRUCKBAUER A, 2003, J AM CHEM SOC, V125, P9834 BRUCKBAUER A, 2004, J AM CHEM SOC, V126, P6508 CAMPBELL M, 2000, NATURE, V404, P53 CHAN EWL, 2002, J AM CHEM SOC, V124, P12238 CLAPP AR, 2004, J AM CHEM SOC, V126, P301 CLARK SL, 1997, MACROMOLECULES, V30, P7237 CLARK SL, 1999, ADV MATER, V11, P1031 CRISP MT, 2003, NANO LETT, V3, P173 CUI XQ, 2003, BIOSENS BIOELECTRON, V18, P59 DANIEL MC, 2004, CHEM REV, V104, P293 DAVIS SA, 2003, CURR OPIN SOLID ST M, V7, P273 DECHER G, 1997, SCIENCE, V277, P1232 DELOUISE LA, 2004, ANAL CHEM, V76, P6915 DEMERS LM, 2002, SCIENCE, V296, P1836 DU H, 2003, J AM CHEM SOC, V125, P4012 FAUL CFJ, 2003, ADV MATER, V15, P673 FORSTER T, 1948, ANN PHYSIK, V2, P55 FRANZL T, 2004, NANO LETT, V4, P1599 GEISSLER M, 2004, ADV MATER, V16, P1249 GINGER DS, 2004, ANGEW CHEM INT EDIT, V43, P30 GOLDMAN ER, 2005, J AM CHEM SOC, V127, P6744 GOSLING JP, 1990, CLIN CHEM, V36, P1408 HAMMOND PT, 2004, ADV MATER, V16, P1271 HAN MY, 2001, NAT BIOTECHNOL, V19, P631 HEALEY BG, 1995, SCIENCE, V269, P1078 HENRIKSEN A, 1999, J BIOL CHEM, V274, P35005 HERNE TM, 1997, J AM CHEM SOC, V119, P8916 JAFFAR S, 2004, NANO LETT, V4, P1421 JEON S, 2004, ADV MATER, V16, P1369 JESSEL N, 2003, ADV MATER, V15, P692 JIANG XP, 2001, ADV MATER, V13, P1669 KAWATA S, 2001, NATURE, V412, P697 KIDAMBI S, 2004, J AM CHEM SOC, V126, P4697 KOTOV NA, 1995, J PHYS CHEM-US, V99, P13065 LANG J, 1999, J PHYS CHEM B, V103, P11393 LEE KB, 2003, J AM CHEM SOC, V125, P5588 LI HT, 2004, ANAL CHEM, V76, P4446 LI HW, 2002, NANO LETTERS, V2, P347 LI HW, 2003, LANGMUIR, V19, P1963 LI HW, 2003, NANOTECHNOLOGY, V14, P220 LI JWJ, 2002, NANO LETTERS, V2, P315 LIMOGES B, 2003, J AM CHEM SOC, V125, P9192 LIU DS, 2003, ANGEW CHEM INT EDIT, V42, P5734 LIVNAH O, 1993, P NATL ACAD SCI USA, V90, P5076 MACBEATH G, 2000, SCIENCE, V289, P1760 MAMEDOV AA, 2001, J AM CHEM SOC, V123, P7738 MAMEDOVA NN, 2001, NANO LETTERS, V1, P281 MAO CD, 1999, NATURE, V397, P144 MAO HB, 2002, ANAL CHEM, V74, P379 MATTOUSSI H, 2000, J AM CHEM SOC, V122, P12142 MEDINTZ IL, 2003, NAT MATER, V2, P630 MICHALET X, 2005, SCIENCE, V307, P538 MICHEL B, 2001, IBM J RES DEV, V45, P697 NIEMEYER CM, 2001, ANGEW CHEM INT EDIT, V40, P4128 NIEMEYER CM, 2002, ANGEW CHEM INT EDIT, V41, P3779 OH E, 2005, J AM CHEM SOC, V127, P3270 PEREZLUNA VH, 1999, J AM CHEM SOC, V121, P6469 PEYRATOUT CS, 2004, ANGEW CHEM INT EDIT, V43, P3762 PRIME KL, 1991, SCIENCE, V252, P1164 PUGLIESE L, 1993, J MOL BIOL, V231, P698 RAIMONDI F, 2005, ANGEW CHEM INT EDIT, V44, P2190 RAO SV, 1999, BIOTECHNOL BIOENG, V65, P389 RIEPL M, 2002, LANGMUIR, V18, P7016 ROGACH AL, 2000, CHEM MATER, V12, P1526 ROSI NL, 2005, CHEM REV, V105, P1547 SEEMAN NC, 2003, NATURE, V421, P427 STRYER L, 1967, P NATL ACAD SCI USA, V58, P719 ULMAN A, 1996, CHEM REV, V96, P1533 VIANELLO F, 2000, BIOTECHNOL BIOENG, V68, P488 WAGNER P, 1995, LANGMUIR, V11, P3867 WANG XZ, 2003, CHEM COMMUN, P474 WANG Y, 2003, J AM CHEM SOC, V125, P2830 WEISS S, 1999, SCIENCE, V283, P1676 WHITESIDES GM, 1991, SCIENCE, V254, P1312 WHITESIDES GM, 2001, ANNU REV BIOMED ENG, V3, P335 WHITESIDES GM, 2002, SCIENCE, V295, P2418 WILSON DL, 2001, P NATL ACAD SCI USA, V98, P13660 WILSON DS, 2003, ANGEW CHEM INT EDIT, V42, P494 WU YM, 1998, ENZYME MICROB TECH, V22, P315 WUISTER SF, 2003, NANO LETT, V3, P503 XIA YN, 1999, CHEM REV, V99, P1823 YING LM, 2002, ANAL CHEM, V74, P1380 YING LM, 2003, P NATL ACAD SCI USA, V100, P14629 YING LM, 2005, PHYS CHEM CHEM PHYS, V7, P2859 YURKE B, 2000, NATURE, V406, P605 ZHOU D, 2003, NANO LETT, V3, P1517 ZHOU DJ, 2002, LANGMUIR, V18, P8278 ZHOU DJ, 2003, ANGEW CHEM INT EDIT, V42, P4934 ZHOU DJ, 2003, LANGMUIR, V19, P10557 ZHOU DJ, 2004, LANGMUIR, V20, P9089 ZHOU DJ, 2005, ADV MATER, V17, P1243 ZHOU DJ, 2005, CHEM COMMUN, P4807ISI:000239797900007_Univ Cambridge, Nanosci Ctr, Cambridge CB3 0FF, England. Sungkyunkwan Univ, Dept Phys, Suwon 440746, South Korea. Sungkyunkwan Univ, Sungkyunkwan Adv Inst Nanotechnol, Inst Basic Sci, Ctr Nanotubes & Nanostruct Composites, Suwon 440746, South Korea. Kang, DJ, Univ Cambridge, Nanosci Ctr, 11 JJ Thomson Ave, Cambridge CB3 0FF, England. djkang@skku.edu file://S:\SALES\_IMPORTANT_STUFF_HERE\Bibliography_Key_Papers\all publications DPN as of 101006 Copy.Data\PDF\2005 Intl JoNanotechnology Zhou Creating Functional Nanostructed M-1803519326\2005 Intl JoNanotechnology Zhou Creating Functional Nanostructed Materials.pdf~? Ahmad, F. Shin, K.2006NDendrimers at the air-water interface: surface dynamics and molecular ordering353-371'International Journal of Nanotechnology32-3dendrimers; air-water interface; monolayers; interfacial properties; isotherms DIP-PEN NANOLITHOGRAPHY; DENDRITIC MACROMOLECULES; THIN-FILMS; LANGMUIR-BLODGETT; BLOCK-COPOLYMERS; AMPHIPHILIC DENDRIMERS; TERMINATED DENDRIMERS; ELECTRICAL-PROPERTIES; POLYETHER DENDRIMERS; MONOLAYERSArticleIn recent years considerable effort has been devoted to the fabrication of molecular devices by exploiting ultra thin organic films. Our attention has been focused on dendrimers, one of the most promising candidates for use in preparing highly functionalised devices due to their flexible architecture and unique properties. Thin films of dendrimers provide better control over the inter-distance and the density of the functional groups. In order to generate highly ordered ultra thin films of dendrimers, a prior understanding of their molecular behaviour is required. This review highlights recent investigations and the contribution of Korean researchers to the study of the molecular behaviour and dynamics of dendrimers at interfaces. Here we emphasise the importance of phase isotherms (air-water interface) in understanding the molecular behaviour, molecular interactions, and molecular assembly, together with factors that permit the molecular behaviour to be tuned and controlled.://000239892500012 Times Cited: 0 Cited References: ADRONOV A, 2000, CHEM COMMUN, P1701 AKIMOTO Y, 2000, CHEM PHYS LETT, V326, P383 ALBRECHT TT, 2000, SCIENCE, V290, P2126 BEILINSKA A, 1996, NUCLEIC ACIDS RES, V24, P2176 CALVERT P, 2001, CHEM MATER, V13, P3299 CARDULLO F, 1998, LANGMUIR, V14, P1955 FAIL CA, 2002, LANGMUIR, V18, P264 FELDER D, 2000, ANGEW CHEM INT EDIT, V39, P201 FRECHET JM, 1994, SCIENCE, V263, P1711 FRECHET JMJ, 1999, CHEM MATER, V11, P1267 GRAYSON SK, 2001, CHEM REV, V101, P3819 GRAYSON SK, 2001, CHEM REV, V101, P3819 HAIM AB, 1997, J AM CHEM SOC, V119, P6197 HARKINS WD, 1952, PHYS CHEM SURFACE FI HAWKER CJ, 1990, J AM CHEM SOC, V112, P7638 HIRANO C, 2005, LANGMUIR, V21, P272 HONG BJ, 2003, LANGMUIR, V19, P2357 HUANG E, 1998, NATURE, V395, P755 HYUN J, 2004, J AM CHEM SOC, V126, P7330 JEONG UY, 2002, ADV MATER, V14, P274 JONAS U, 1995, CHEM-EUR J, V1, P243 JUNG SB, 2003, SYNTHETIC MET 1, V135, P75 JUNG SB, 2003, THIN SOLID FILMS, V438, P27 KAMPF JP, 1999, LANGMUIR, V15, P227 KANG JS, 2004, MAT SCI ENG C-BIO S, V24, P281 KANG SZ, 2003, CHEM PHYS LETT, V370, P542 KHOPADE AJ, 2002, NANO LETTERS, V2, P415 KIM H, 2004, BIOMACROMOLECULES, V5, P822 KIM SO, 2003, NATURE, V424, P411 KIRTON GF, 1998, PHYSICA B, V248, P184 KNAPEN JWJ, 1994, NATURE, V372, P659 LANGMUIR I, 1917, J AM CHEM SOC, V39, P1848 LIU YL, 1997, J AM CHEM SOC, V119, P8720 MANSFIELD ML, 1993, MACROMOLECULES, V26, P4262 MANSFIELD ML, 1996, POLYMER, V37, P3835 MATSUI J, 2004, J AM CHEM SOC, V126, P3708 MCKENDRY R, 2002, NANO LETTERS, V2, P713 MOUREY TH, 1992, MACROMOLECULES, V25, P2401 NEWKOME GR, 1985, J ORG CHEM, V50, P2003 NEWKOME GR, 1986, DENDRITIC MOL CONCEP NIERENGARTEN JF, 2001, J AM CHEM SOC, V123, P9743 NIU SJ, 2003, MACROMOLECULES, V36, P2428 NIWA D, 2004, J PHYS CHEM B, V108, P3240 PAO WJ, 2001, PHYS CHEM B, V105, P2170 PARK C, 2001, MACROMOLECULES, V34, P2602 PARK M, 1997, SCIENCE, V276, P1401 PORTER LA, 2002, NANO LETT, V2, P1369 RAYLEIGH L, 1890, P ROY SOC LOND A MAT, V48, P127 REICHMANIS E, 1999, ACCOUNTS CHEM RES, V32, P659 RICHTEREGGER DL, 2001, ANAL CHEM, V73, P5743 ROBERTS G, 1990, LANGMUIR BLODGETT FI SAVILLE PM, 1993, J PHYS CHEM-US, V97, P293 SAVILLE PM, 1995, J PHYS CHEM-US, V99, P8283 SCHENNING APHJ, 1998, J AM CHEM SOC, V120, P8199 SEO YS, 2002, LANGMUIR, V18, P5927 SEO YS, 2004, NANO LETT, V4, P483 SEYREK E, 2004, J PHYS CHEM B, V108, P10168 SHIN K, 2001, LANGMUIR, V17, P4955 SIDORENKO A, 2000, LANGMUIR, V16, P10569 SOHN BH, 2001, J AM CHEM SOC, V123, P12734 SWEET YS, 1997, J CHEM MAT, V7, P1199 TANAKA K, 2003, LANGMUIR, V19, P1196 TOMALIA DA, 1985, POLYM J, V17, P117 TOMALIA DA, 1994, 5728461, US TSUKRUK VV, 1998, ADV MATER, V10, P253 TULLY DC, 2001, CHEM COMMUN, P1229 WALLRAFF GM, 1999, CHEM REV, V99, P1801 WARD M, 2000, ANNU REP PROG CHEM A, V96, P354 WEENER JW, 2000, ADV MATER, V12, P1001 WELLS M, 1996, J AM CHEM SOC, V118, P3988 XU G, 2002, LANGMUIR, V16, P1834 YANG XM, 2000, MACROMOLECULES, V33, P9575 YOON DK, 2003, LANGMUIR, V19, P1154 YOON HC, 2000, ANAL CHEM, V72, P922 ZENG FW, 1997, CHEM REV, V97, P1681 ZHANG L, 2000, LANGMUIR, V16, P3813 ZIMMERMAN SC, 1996, SCIENCE, V271, P1095ISI:000239892500012Gwangju Inst Sci & Technol, Dept Mat Sci & Engn, Kwangju 500712, South Korea. Shin, K, Gwangju Inst Sci & Technol, Dept Mat Sci & Engn, Kwangju 500712, South Korea. kwshin@gist.ac.krinternal-pdf://2006 Intl Journal of Nanotech. Ahmad Dendrimers at the air-w-1003355663/2006 Intl Journal of Nanotech. Ahmad Dendrimers at the air-water interface.pdfXcxournal of Nanotech. Ahmad Dendrimers at the air-water interface.pdf d~?:Jung, J. M. Kwon, K. Y. Ha, T. H. Chung, B. H. Jung, H. T.2006lGold-conjugated protein nanoarrays through block-copolymer lithography: From fabrication to biosensor design 1010-1015Small28-9biosensors; block copolymers; lithography; nanoparticles; proteins SELF-ASSEMBLED MONOLAYERS; SURFACE-PLASMON RESONANCE; DIP-PEN NANOLITHOGRAPHY; CHEMISTRY; ARRAYS; CENTIMETER; SCALEArticleAug://000239717500012 Times Cited: 0 Cited References: ARNOLD M, 2004, CHEMPHYSCHEM, V5, P383 BES L, 2003, MACROMOLECULES, V36, P2493 BOCKSTALLER MR, 2005, ADV MATER, V17, P1331 BRUCKBAUER A, 2004, J AM CHEM SOC, V126, P6508 CHOI DG, 2004, NANOTECHNOLOGY, V15, P970 DANIEL MC, 2004, CHEM REV, V104, P293 DENIS FA, 2002, LANGMUIR, V18, P819 DUVERGER E, 2003, BIOCHIMIE, V85, P167 FALCONNET D, 2004, NANO LETT, V4, P1909 GOODING JJ, 1999, TRAC-TREND ANAL CHEM, V18, P525 GREEN NM, 1990, METHOD ENZYMOL, V184, P51 HAGA T, 2000, G PROTEIN COUPLED RE HOFF JD, 2004, NANO LETT, V4, P853 HOOK F, 2001, LANGMUIR, V17, P8305 JELINEK R, 2004, CHEM REV, V104, P5987 JEOUNG E, 2001, LANGMUIR, V17, P6396 JUNG JM, 2004, ANAL BIOCHEM, V330, P251 KANG MC, 2005, SMALL, V1, P69 KUMER N, 2005, LANGMUIR, V21, P6652 LEE KB, 2002, SCIENCE, V295, P1702 LI HW, 2003, LANGMUIR, V19, P1963 LIENER IE, 1986, LECTINS PROPERTIES F, P33 MICHEL R, 2002, LANGMUIR, V18, P8580 NIEMEYER CM, 2004, NANOBIOTECHNOLOGY, P31 PARK M, 1997, SCIENCE, V276, P1401 PARK TJ, 2004, J AM CHEM SOC, V126, P10512 SALAITA K, 2005, SMALL, V1, P940 SHIBUICHI S, 1996, J PHYS CHEM-US, V100, P19512 VEGA RA, 2005, ANGEW CHEM INT EDIT, V44, P6013 VEGA RA, 2005, ANGEW CHEM, V117, P6167 WHITESIDES GM, 1990, LANGMUIR, V6, P87 ZHANG GJ, 2005, SMALL, V1, P833ISI:000239717500012YKorea Adv Inst Sci & Technol, Dept Chem & Biomol Engn, Lab Organ Optoelect Mat, Taejon 305701, South Korea. Korea Res Inst Biosci & Biotechnol, Res Ctr, Taejon 305600, South Korea. Chung, BH, Korea Adv Inst Sci & Technol, Dept Chem & Biomol Engn, Lab Organ Optoelect Mat, BK-21, Taejon 305701, South Korea. chungbh@kribb.re.kr heetae@kaist.ac.krinternal-pdf://2006 Small Jung Gold-Conjugated Protein Nanoarrays-1959699215/2006 Small Jung Gold-Conjugated Protein Nanoarrays.pdf %' Condensation and Brige Formation.pdf ~?jChristman, K. L. Requa, M. V. Enriquez-Rios, V. D. Ward, S. C. Bradley, K. A. Turner, K. L. Maynard, H. D.20064Submicron streptavidin patterns for protein assembly 7444-7450Langmuir2217DIP-PEN NANOLITHOGRAPHY; LAYER-EXPANSION TECHNIQUE; ANTHRAX TOXIN RECEPTOR; PROTECTIVE ANTIGEN; FOCAL ADHESIONS; OXIDE SURFACES; MOSAIC-VIRUS; LETHAL TOXIN; LITHOGRAPHY; NANOSTRUCTURESArticleAugMicron and submicron-scale features of aldehyde functionality were fabricated in polymer films by photolithography to develop a platform for protein immobilization and assembly at a biologically relevant scale. Films containing the pH-reactive polymer poly(3,3'-diethoxypropyl methacrylate) and a photoacid generator (PAG) were patterned from 500 nm to 40 mu m by exposure to 365 nm (i-line) light. Upon PAG activation and hydrolysis of acetals, aldehyde groups formed. After the films were incubated with a biotinylated aldehyde reactive probe, the X-ray photoelectron spectroscopy results were consistent with biotin being attached to the surface. The background was subsequently passivated by flood exposure and incubation with an aminooxy-terminated poly(ethylene glycol), resulting in a 98% reduction in nonspecific protein adsorption. Protein patterning and assembly was demonstrated using streptavidin, biotinylated anthrax toxin receptor-1, and the protective antigen moiety of anthrax toxin and confirmed by fluorescence microscopy and atomic force microscopy (AFM). AFM demonstrated that 500 nm protein features were achieved. Because of the abundance of biotinylated proteins, this methodology provides a platform for protein immobilization and assembly for various applications in biotechnology.://000239596300057 Times Cited: 0 Cited References: AGARWAL G, 2003, J AM CHEM SOC, V125, P580 AOKI A, 1999, LANGMUIR, V15, P7418 ASTIER Y, 2005, CURR OPIN CHEM BIOL, V9, P576 BHATIA SK, 1992, J AM CHEM SOC, V114, P4432 BRADLEY KA, 2001, NATURE, V414, P225 BRADLEY KA, 2003, BIOCHEM PHARMACOL, V65, P309 BRADLEY KA, 2003, J BIOL CHEM, V278, P49342 BURRIDGE K, 1988, ANNU REV CELL BIOL, V4, P487 BURRIDGE K, 1996, ANNU REV CELL DEV BI, V12, P463 CASE MA, 2003, NANO LETT, V3, P425 CHRISTMAN KL, 2005, LANGMUIR, V21, P8389 CSUCS G, 2003, LANGMUIR, V19, P6104 FALCONNET D, 2004, NANO LETT, V4, P1909 FRIEDLANDER AM, 1986, J BIOL CHEM, V261, P7123 HARRIS JM, 1992, POLYETHYLENE GLYCOL HOFF JD, 2004, NANO LETT, V4, P853 HONG L, 2003, LANGMUIR, V19, P1966 HONG L, 2003, SURF COAT TECH, V169, P211 HYUN J, 2002, NANO LETT, V2, P1203 ICHINOSE N, 1993, CHEM LETT, P1961 KENSETH JR, 2001, LANGMUIR, V17, P4105 KUMAR A, 1993, APPL PHYS LETT, V63, P2002 KWAK SK, 2004, MAT SCI ENG C-BIO S, V24, P151 LEE KB, 2002, SCIENCE, V295, P1702 LEE KB, 2004, NANO LETT, V4, P1869 LEE KJ, 2004, LANGMUIR, V20, P1812 LEMIEUX GA, 1998, TRENDS BIOTECHNOL, V16, P506 LI HW, 2003, LANGMUIR, V19, P1963 LIM JH, 2003, ANGEW CHEM INT EDIT, V42, P2309 LIU J, 1996, COLLOID SURFACE B, V8, P25 MILNE JC, 1993, MOL MICROBIOL, V10, P647 MIYAMOTO S, 1995, J CELL BIOL, V131, P791 NAKAGAWA M, 2002, COLLOID SURFACE A, V204, P1 NAM JM, 2004, ANGEW CHEM INT EDIT, V43, P1246 NOY A, 2002, NANO LETTERS, V2, P109 NURAJE N, 2004, J AM CHEM SOC, V126, P8088 PENA DJ, 2003, LANGMUIR, V19, P9028 PETOSA C, 1997, NATURE, V385, P833 PLATEN J, 2006, SENSORS-BASEL, V6, P361 POGHOSSIAN A, 2005, ELECTROCHIM ACTA, V51, P838 RENAULTT JP, 2003, J PHYS CHEM B, V107, P703 RYAN D, 2004, LANGMUIR, V20, P9080 SCHLICK TL, 2005, J AM CHEM SOC, V127, P3718 SCOBIE HM, 2005, J INFECT DIS, V192, P1047 SHAW LM, 1990, J CELL BIOL, V110, P2167 SMITH JC, 2003, NANO LETT, V3, P883 VOROS J, 2005, MRS BULL, V30, P202 VOSSMEYER T, 1998, J APPL PHYS, V84, P3664 WADUMESTHRIGE K, 1999, LANGMUIR, V15, P8580 WEBER PC, 1989, SCIENCE, V243, P85 WIGELSWORTH DJ, 2004, J BIOL CHEM, V279, P23349 WILSON DL, 2001, P NATL ACAD SCI USA, V98, P13660 XIA YN, 1998, ANGEW CHEM INT EDIT, V37, P551 YIN HB, 2004, NUCLEIC ACIDS RES, V32 ZHOU DJ, 2003, LANGMUIR, V19, P10557ISI:000239596300057Univ Calif Los Angeles, Calif NanoSyst Inst, Dept Microbiol Immunol & Mol Genet, Dept Chem & Biochem, Los Angeles, CA 90095 USA. Univ Calif Santa Barbara, Calif Nanosyst Inst, Dept Mech Engn, Santa Barbara, CA 93106 USA. Maynard, HD, Univ Calif Los Angeles, Calif NanoSyst Inst, Dept Microbiol Immunol & Mol Genet, Dept Chem & Biochem, Los Angeles, CA 90095 USA. maynard@chem.ucla.eduinternal-pdf://2006_Langmuir_Submicron streptavidin patterns for protein assembly-3671179535/2006_Langmuir_Submicron streptavidin patterns for protein assembly.pdf 1Formation-3272973328/2006 JPC Sacha Induced Water;~?SBlattler, T. Huwiler, C. Ochsner, M. Stadler, B. Solak, H. Voros, J. Grandin, H. M.2006&Nanopatterns with biological functions 2237-2264)Journal of Nanoscience and Nanotechnology68Nnanopatterns; biological functions; lithography DIP-PEN NANOLITHOGRAPHY; SELF-ASSEMBLED MONOLAYERS; ELECTRON-BEAM LITHOGRAPHY; SURFACE-PLASMON RESONANCE; POLY(L-LYSINE)-G-POLY(ETHYLENE GLYCOL) LAYERS; EUV INTERFERENCE LITHOGRAPHY; NANOSCALE OPTICAL BIOSENSOR; NANO-STRUCTURED SURFACES; BLOCK-COPOLYMER MICELLES; SILICON-OXIDE SURFACESReviewAugjBoth curiosity and a desire for efficiency have advanced our ability to manipulate materials with great precision on the micrometer and, more recently, on the nanometer scale. Certainly, the semiconductor and integrated circuit industry has put the pressure on scientist and engineers to develop better and faster nanofabrication techniques. Furthermore, our curiosity as to how life works, and how it can be improved from a medical perspective, stands to gain a great deal from advances in nanotechnology. Novel nanofabrication techniques are opening up the possibilities for mimicking the inherently nano-world of the cell, i.e., the nanotopographies of the extracellular matrix (ECM) and the nanochemistry presented on both the cell membrane and the ECM. In addition, biosensing applications that rely on fabrication of high-density, precision arrays, e.g., DNA or gene chips and protein arrays, will gain significantly in efficiency and, thus, in usefulness once it becomes possible to fabricate heterogeneous nanoarrays. Clearly, continued advances in nanotechnology are desired and required for advances in biotechnology. In this review, we describe the leading techniques for generating nanopatterns with biological function including parallel techniques such as extreme ultraviolet interference lithography (EUV-IL), soft-lithographic techniques (e.g., replica molding (RM) and microcontact printing (mu CP)), nanoimprint lithography (NIL), nanosphere lithography (NSL) (e.g., colloid lithography or colloidal block-copolymer micelle lithography) and the nanostencil technique, in addition to direct-writing techniques including e-bearn lithography (EBL), focused ion-beam lithography (FIBL) and dip-pen nanolithography (DPN). Details on how the patterns are generated, how biological function is imparted to the nanopatterns, and examples of how these surfaces can and are being used for biological applications will be presented. This review further illustrates the rapid pace by which advances are being made in the field of nanobiotechnology, owing to an increasing number of research endeavors, for an ever increasing number of applications.://000239780500003 /Times Cited: 0 Cited References: AGARWAL G, 2003, J AM CHEM SOC, V125, P580 AGARWAL G, 2003, J AM CHEM SOC, V125, P7408 AIZAWA M, 2005, J AM CHEM SOC, V127, P8932 AMIJI M, 1992, BIOMATERIALS, V13, P682 AMRO NA, 2000, LANGMUIR, V16, P3006 ANDERSSON AS, 2003, BIOMATERIALS, V24, P3427 ANDRES RP, 1996, SCIENCE, V273, P1690 ARNOLD M, 2004, CHEMPHYSCHEM, V5, P383 BARBUCCI R, 2003, J MATER SCI-MATER M, V14, P721 BEARINGER JP, 1997, LANGMUIR, V13, P5175 BENALI M, 2002, LANGMUIR, V18, P872 BERDONDINI L, 2005, BIOSENS BIOELECTRON, V21, P167 BERNARD A, 1998, LANGMUIR, V14, P2225 BERNARD A, 2000, ADV MATER, V12, P1067 BIETSCH A, 2000, J APPL PHYS, V88, P4310 BOHM I, 1999, APPL SURF SCI, V141, P237 BREHMER M, 2003, J DISPER SCI TECHNOL, V24, P291 BREULMANN M, 2000, 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Paul Scherrer Inst, Lab Micro & Nanotechnol, Villigen, Switzerland. Grandin, HM, ETH, Dept Mat, BioInterface Grp, Lab Surface Sci & Technol, Zurich, Switzerland.K$~?%Ariga, K. Nakanishi, T. Michinobu, T.2006Immobilization of biomaterials to nano-assembled films (self-assembled monolayers, Langmuir-Blodgett films, and layer-by-layer assemblies) and their related functions 2278-2301)Journal of Nanoscience and Nanotechnology68self-assembled monolayer (SAM); Langmuir-Blodgett (LB) film; layer-by-layer (LBL) assembly; protein; DNA; molecular recognition; sensor; reactor AIR-WATER-INTERFACE; QUARTZ-CRYSTAL-MICROBALANCE; FLAVIN ADENINE-DINUCLEOTIDE; ULTRATHIN MULTILAYER FILMS; ORGANIC-INORGANIC HYBRID; DIP-PEN NANOLITHOGRAPHY; POROUS-GLASS PLATE; TRIPEPTIDE-CONTAINING AMPHIPHILES; DIRECTED PROTEIN IMMOBILIZATION; FORCE MICROSCOPIC OBSERVATIONReviewAugFor utilization of highly sophisticated functions of biomaterials in nano-scale functional systems, immobilization of biomaterials on artificial devices such as electrodes via thin film technology is one of the most powerful strategies. In this review, we focus on three major organic ultrathin films, self-assembled monolayers (SAM), Langmuir-Blodgett (LB) films, and layer-by-layer (LBL) assemblies, and from the viewpoints of biomaterial immobilization, typical examples and recent progresses in these film technologies are described. The SAM method allows facile contact between biomaterials and man-made devices, and well used for bio-related sensors. In addition, recent micro-fabrication techniques such as micro-contact printing and dip-pen nanolithography were successfully applied to preparation of biomaterial patterning. A monolayer at the air-water interface, which is a unit structure of LB films, provides a unique environment for recognition of aqueous biomaterials. Recognition and immobilization of various biomaterials including nucleotides, nucleic acid bases, amino acids, sugars, and peptides were widely investigated. The LB film can be also used for immobilization of enzymes in an ultrathin film on an electrode, resulting in sensor application. The LBL assembling method is available for wide range of biomaterials and provides great freedom in designs of layered structures. These advantages are reflected in preparation of thin-film bio-reactors where multiple kinds of enzymes sequentially operate. LBL assemblies were also utilized for sensors and drug delivery systems. 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Supermol Grp, Tsukuba, Ibaraki 3050044, Japan. Ariga, K, Natl Inst Mat Sci, Supermol Grp, 1-1 Namiki, Tsukuba, Ibaraki 3050044, Japan.`~?Naujoks, N. Stemmer, A.2006PCharge patterns as templates for the assembly of layered miomolecular structures 2445-2450)Journal of Nanoscience and Nanotechnology68charge writing; nanofabrication; guided self-assembly; AFM lithography; avidin-biotin reaction DIP-PEN NANOLITHOGRAPHY; PROBE FORCE MICROSCOPY; DRYING DROPS; GAS-PHASE; PARTICLES; SURFACE; LITHOGRAPHY; DEPOSITION; FABRICATION; INTERFACEArticleAugElectric fields are used to guide the assembly of biomolecules in predefined geometric patterns on solid substrates. Local surface charges serve as templates to selectively position proteins on thin-film polymeric electret layers, thereby creating a basis for site-directed layered assembly of biomolecular structures. Charge patterns are created using the lithographic capabilities of an atomic force microscope, namely by applying voltage pulses between a conductive tip and the sample. Samples consist of a poly(methyl methacrylate) layer on a p-doped silicon support. Subsequently, the sample is developed in a water-in-oil emulsion, consisting of a dispersed aqueous phase containing biotin-modified immunoglobulinG molecules, and a continuous nonpolar, insulating oil phase. The electrostatic fields cause a net force of (di)electrophoretic nature on the droplet, thereby guiding the proteins to the predefined locations. Due to the functionalization of the immunoglobulinG molecules with biotin-groups, these patterns can now be used to initiate the localized layer-by-layer assembly of biomolecules based on the avidin-biotin mechanism. By binding 40 nm sized biotin-labelled beads to the predefined locations via a streptavidin linker, we verify the functionality of the previously deposited immunoglobulinG-biotin. All assembly steps following the initial deposition of the immunoglobulinG from emulsion can conveniently be conducted in aqueous solutions. Results show that pattern definition is maintained after immersion into aqueous solution.://000239780500025 Times Cited: 0 Cited References: AGARWAL G, 2003, J AM CHEM SOC, V125, P7408 BERNARD A, 2001, NAT BIOTECHNOL, V19, P866 DEEGAN RD, 2000, PHYS REV E, V61, P475 DICKINSON E, 1999, COLLOID SURFACE B, V15, P161 DOUVAS AM, 2005, ANAL BIOANAL CHEM, V381, P1027 FALCONNET D, 2004, ADV FUNCT MATER, V14, P749 FEDER J, 1976, J APPL PHYS, V47, P1741 FENG J, 2004, COLLOID SURFACE B, V36, P177 FUDOUZI H, 2001, J NANOPART RES, V3, P193 FUDOUZI H, 2002, ADV MATER, V14, P1649 FUDOUZI H, 2002, LANGMUIR, V18, P7648 GARNO JC, 2002, LANGMUIR, V18, P8186 HOFF JD, 2004, NANO LETT, V4, P853 JACOBS HO, 1997, ULTRAMICROSCOPY, V69, P39 JACOBS HO, 2001, SCIENCE, V291, P1763 KAMYSHNY A, 1997, COLLOID SURFACE B, V9, P147 KAMYSHNY A, 1999, J COLLOID INTERF SCI, V212, P74 KIKUKAWA A, 1995, APPL PHYS LETT, V66, P3510 KRINKE TJ, 2001, APPL PHYS LETT, V78, P3708 KRINKE TJ, 2002, PART PART SYST CHAR, V19, P321 LASH JL, 1995, PROTEINS INTERFACES, V2 LEE KB, 2003, J AM CHEM SOC, V125, P5588 MCCLEMENTS DJ, 2004, CURR OPIN COLLOID IN, V9, P305 MESQUIDA P, 2002, MICROELECTRON ENG, V61, P671 MESQUIDA P, 2002, SCANNING, V24, P117 MESQUIDA P, 2002, SURF INTERFACE ANAL, V33, P159 MORT J, 1989, ANATOMY XEROGRAPHY I NAUJOKS N, 2004, COLLOID SURFACE A, V249, P69 NAUJOKS N, 2005, MICROELECTRON ENG, V78, P331 NONNENMACHER M, 1991, APPL PHYS LETT, V58, P2921 SESSLER GM, 1987, ELECTRETS STEMMER A, 2002, CHIMIA, V56, P573 WHITESIDES GM, 2001, ANNU REV BIOMED ENG, V3, P335 WRIGHT WMD, 1998, NANOTECHNOLOGY, V9, P133 YAKHNO T, 2005, NONLINEAR DYNAM, V39, P369 YAP FL, 2005, LANGMUIR, V21, P5233ISI:000239780500025~ETH, Nanotechnol Grp, CH-8092 Zurich, Switzerland. Naujoks, N, ETH, Nanotechnol Grp, Tannenstr 3, CH-8092 Zurich, Switzerland.0 Ζ~?`Schonherr, H. Degenhart, G. H. Dordi, B. Feng, C. L. Rozkiewicz, D. I. Shovsky, A. Vancso, G. J.2006Organic and macromolecular films and assemblies as (bio)reactive platforms: From model studies on structure-reactivity relationships to submicrometer patterning169-208,Ordered Polymeric Nanostructures at Surfaces200BerlinSpringer-Verlag Berlin;biointerfacing; micropatterning; nanopatterning; polymer thin films; surface reactivity ATOMIC-FORCE MICROSCOPY; SURFACE-PLASMON RESONANCE; SUPPORTED LIPID-BILAYERS; QUARTZ-CRYSTAL MICROBALANCE; AQUEOUS 2-PHASE EXTRACTION; NANOMETER-SCALE; GOLD SURFACES; THIN-FILMS; ALKANETHIOLATE MONOLAYERS; PHOSPHOLIPID-BILAYERS#In this contribution we review our recent progress in studies that aim at the understanding of the relationship between structure and surface reactivity of organic thin films on the one hand, and at the micro- and nanofabrication of bioreactive or biocompatible platforms on the other hand. Self-assembled monolayers (SAMs) of n,n'-dithiobis (N-hydroxysuccinimidyl-n-alkano ate) exposing NHS reactive ester groups were studied as model systems for immobilization reactions of DNA, proteins, and receptors. Reaction kinetics and activation energies were determined quantitatively at length scales ranging from millimeters down to nanometers using, for example, surface infrared spectroscopy and in situ inverted chemical force microscopy (iCFM), respectively. The increase in conformational order with increasing alkane segment length was found to result in reduced reactivity due to steric crowding. This drawback of highly organized monolayer architectures and the inherently limited loading can be circumvented by utilizing well-defined macromolecular thin films. Using amine-terminated polyamidoamine (PAMAM) dendrimers immobilized via soft lithography, as well as scanning probe lithography (SPL) approaches (dip-pen nanolithography, DPN) on NHS ester surfaces, robust micrometer and submicrometer patterned (bio)reactive surfaces, which allow one to achieve high molecular loading in coupling reactions for chip-based assays and sensor surfaces, were fabricated. Covalent coupling afforded the required robustness of the patterned assemblies. Finally, we address micro- and nanopatterned bilayer-based systems. SPL was applied in order to fabricate nanoscale biocompatible supramolecular architectures on solid supports. The adsorption of vesicles onto lipid bilayers was spatially controlled and directed in situ with nanometer-scale precision using SPL. This methodology, which provides a platform for research on proteins incorporated in the lipid bilayers comprising the vesicles, does not require that the vesicles are chemically labeled in order to guide their deposition.://000239275000007 Advances in Polymer Science"Times Cited: 0 Cited References: AHMAD J, 1990, LANGMUIR, V6, P1797 ALLARA DL, 1995, BIOSENS BIOELECTRON, V10, P771 AMIRGOULOVA EV, 2004, CHEMPHYSCHEM, V5, P552 AULETTA T, 2004, ANGEW CHEM INT EDIT, V43, P369 BAIN CD, 1989, LANGMUIR, V5, P1370 BASELT DR, 1994, J APPL PHYS, V76, P33 BENNINGHOVEN A, 1994, ANGEW CHEM INT EDIT, V33, P1023 BENTERS R, 2001, CHEMBIOCHEM, V2, P686 BENTERS R, 2002, NUCLEIC ACIDS RES, V30, E1 BERGER CEH, 1995, LANGMUIR, V11, P4188 BERTILSSON L, 1993, LANGMUIR, V9, P141 BEYER D, 1996, ANGEW CHEM INT EDIT, V35, P1682 BOUKOBZA E, 2001, J PHYS CHEM B, V105, P12165 BOXER SG, 2000, CURR OPIN CHEM BIOL, V4, P704 CAMILLONE N, 1993, J CHEM PHYS, V98, P3503 CARPICK RW, 1997, CHEM REV, V97, P1163 CASE MA, 2003, NANO LETT, V3, P425 CASSIE ABD, 1948, DISCUSS FARADAY SOC, V3, P11 CHAPMAN RG, 2001, LANGMUIR, V17, P1225 CHATELIER RC, 1995, LANGMUIR, V11, P4122 CHECHIK V, 1997, LANGMUIR, V13, P6354 CHECHIK V, 1998, LANGMUIR, V14, P99 CHECHIK V, 2000, ADV MATER, V12, P1161 CHEE M, 1996, SCIENCE, V274, P610 CHEN Q, 2004, CHEM MATER, V16, P614 CLARK JH, 1996, CHEM SOC REV, V25, P303 CLINE GW, 1988, J ORG CHEM, V53, P3583 CREAGER SE, 1994, LANGMUIR, V10, P3675 CREMER PS, 1999, J AM CHEM SOC, V121, P8130 CREMER PS, 1999, LANGMUIR, V15, P3893 DAVID C, 1996, MICROELECTRON ENG, V30, P57 DEARO JA, 1997, CHEM PHYS LETT, V277, P532 DEGENHART GH, 2004, LANGMUIR, V20, P6216 DELAMARCHE E, 1994, LANGMUIR, V10, P2869 DORDI B, 2003, LANGMUIR, V19, P5780 DORDI B, 2004, EUR POLYM J, V40, P939 DORDI B, 2004, SURF SCI, V570, P57 DUBOIS LH, 1992, ANNU REV PHYS CHEM, V43, P437 DUFRENE YF, 1997, LANGMUIR, V13, P4779 DUHACHEK SD, 2000, ANAL CHEM, V72, P3709 EVANS SD, 1998, LANGMUIR, V14, P6436 EVERHART DS, 1999, CHEMTECH, V29, P30 FALCONNET D, 2004, ADV FUNCT MATER, V14, P749 FERRETTI S, 2000, TRAC-TREND ANAL CHEM, V19, P530 FINKLEA HO, 1986, LANGMUIR, V2, P239 FODOR SPA, 1991, SCIENCE, V251, P767 FREY BL, 1996, ANAL CHEM, V68, P3187 FRISBIE CD, 1994, SCIENCE, V265, P2071 FRUTOS AG, 2000, LANGMUIR, V16, P2192 FULGHUM JE, 1999, J ELECTRON SPECTROSC, V100, P331 GEHRKE SH, 1998, BIOTECHNOL BIOENG, V58, P416 GINGER DS, 2004, ANGEW CHEM INT EDIT, V43, P30 GODWIN A, 2001, ANGEW CHEM INT EDIT, V40, P594 GONG P, 2004, SURF SCI, V570, P67 GROVES JT, 1997, SCIENCE, V275, P651 GROVES JT, 2002, ACCOUNTS CHEM RES, V35, P149 HAN WQ, 1997, SCIENCE, V277, P1287 HARDER P, 1998, J PHYS CHEM B, V102, P426 HEIBEL C, 1998, ACS SYM SER, V695, P104 HILLBORG H, 1998, POLYMER, V39, P1991 HILLBORG H, 2004, LANGMUIR, V20, P785 HOLMLIN RE, 2001, LANGMUIR, V17, P2841 HOVIS JS, 2000, LANGMUIR, V16, P894 HOVIS JS, 2001, LANGMUIR, V17, P3400 HU K, 1997, LANGMUIR, V13, P5114 HUANG JY, 1994, LANGMUIR, V10, P626 HUANG NP, 2001, LANGMUIR, V17, P489 ISRAELACHVILI JN, 1991, INTERMOLECULAR SURFA JASCHKE M, 1996, J PHYS CHEM-US, V100, P2290 JENKINS ATA, 1999, J AM CHEM SOC, V121, P5274 JENKINS ATA, 2002, LANGMUIR, V18, P3176 JEROME C, 2003, CHEM COMMUN, V2500 JOHNSON KL, 1971, P ROY SOC LOND A MAT, V324, P301 JOYCE SA, 1992, APPL PHYS LETT, V60, P1175 JUNG LS, 2000, J AM CHEM SOC, V122, P4177 KANE RS, 2003, LANGMUIR, V19, P2388 KHADEMHOSSEINI A, 2003, ADV MATER, V15, P1995 KIM JM, 2003, ADV MATER, V15, P1118 KUMAR A, 1994, LANGMUIR, V10, P1498 KUMAR A, 1994, SCIENCE, V263, P60 KUMAR S, 2000, LANGMUIR, V16, P9936 KUNG LA, 2000, LANGMUIR, V16, P6773 LACKOWSKI WM, 1999, LANGMUIR, V15, P7632 LAHANN J, 2002, LANGMUIR, V18, P3632 LAHIRI J, 1999, ANAL CHEM, V71, P777 LAIBINIS PE, 1995, J PHYS CHEM-US, V99, P7663 LARSEN NB, 1997, J AM CHEM SOC, V119, P3017 LEE TR, 1994, LANGMUIR, V10, P741 LI HW, 2002, NANO LETTERS, V2, P347 LI HW, 2003, LANGMUIR, V19, P1963 LIEBAU M, 2001, ADV FUNCT MATER, V11, P147 LIPOWSKY R, 1991, MOL CRYST LIQ CRYST, V202, P17 LIU GY, 2000, ACCOUNTS CHEM RES, V33, P457 LOCKHART DJ, 2000, NATURE, V405, P827 LUSSI JW, 2004, PROG SURF SCI, V76, P55 MALMQVIST M, 1997, CURR OPIN CHEM BIOL, V1, P378 MENDES PM, 2004, CURR OPIN COLLOID IN, V9, P236 MIRKIN CA, 1992, ANNU REV PHYS CHEM, V43, P719 MIZES HA, 1991, APPL PHYS LETT, V59, P2901 MORIGAKI K, 2001, ANGEW CHEM INT EDIT, V40, P172 MORIGAKI K, 2003, LANGMUIR, V19, P6994 MRKSICH M, 2000, CHEM SOC REV, V29, P267 NEOGI P, 1993, J CHEM SOC CHEM COMM, P1134 NIEMEYER CM, 1999, ANGEW CHEM INT EDIT, V38, P2865 NISMAN R, 1994, LANGMUIR, V10, P1667 NOY A, 1997, ANNU REV MATER SCI, V27, P381 NUZZO RG, 1983, J AM CHEM SOC, V105, P4481 OSTUNI E, 1999, COLLOID SURFACE B, V15, P3 OSTUNI E, 2001, LANGMUIR, V17, P5605 OSTUNI E, 2001, LANGMUIR, V17, P6336 OVERNEY RM, 1992, NATURE, V359, P133 PAOLESSE R, 1998, SENSOR ACTUAT B-CHEM, V47, P70 PATHAK S, 2004, LANGMUIR, V20, P6075 PIRRUNG MC, 2002, ANGEW CHEM INT EDIT, V41, P1277 PLANT AL, 1993, LANGMUIR, V9, P2764 POIRIER GE, 1997, CHEM REV, V97, P1117 PORTER MD, 1987, J AM CHEM SOC, V109, P3559 PRIME KL, 1991, SCIENCE, V252, P1164 PRIME KL, 1993, J AM CHEM SOC, V115, P10714 PRUCKER O, 1998, MACROMOLECULES, V31, P592 PRUCKER O, 1998, MACROMOLECULES, V31, P602 PUTKA CS, 2002, BIOTECHNOL BIOENG, V80, P139 RADMACHER M, 1994, BIOPHYS J, V66, P2159 REVIAKINE I, 2000, LANGMUIR, V16, P1806 RICCO AJ, 1998, ACCOUNTS CHEM RES, V31, P289 RINGSDORF H, 1988, ANGEW CHEM INT EDIT, V27, P113 ROWAN B, 2002, LANGMUIR, V18, P9914 RUHE J, 2001, ABSTR PAP AM CHEM 1, V221, U356 SABATANI E, 1987, J ELECTROANAL CH INF, V219, P365 SACKMANN E, 1996, SCIENCE, V271, P43 SAGIV J, 1980, J AM CHEM SOC, V102, P92 SCHENA M, 1995, SCIENCE, V270, P467 SCHENA M, 2003, MICROARRAY ANAL SCHMIDT P, 2000, POLYMER, V41, P4267 SCHONHERR H, 1997, MACROMOLECULES, V30, P6391 SCHONHERR H, 1998, LANGMUIR, V14, P2801 SCHONHERR H, 2000, CHEM MATER, V12, P3689 SCHONHERR H, 2000, J AM CHEM SOC, V122, P3679 SCHONHERR H, 2000, MACROMOLECULES, V33, P4532 SCHONHERR H, 2001, ACS SYM SER, V781, P36 SCHONHERR H, 2003, LANGMUIR, V19, P10843 SCHONHERR H, 2004, LANGMUIR, V20, P11600 SCHONHERR H, 2004, LANGMUIR, V20, P7308 SCHREIBER F, 2004, J PHYS-CONDENS MAT, V16, P881 SCHULZE A, 2001, NAT CELL BIOL, V3, P190 SEIFERT U, 1997, ADV PHYS, V46, P13 SIEGERS C, 2004, CHEM-EUR J, V10, P2831 SIGNAL GB, 1996, ANAL CHEM, V68, P490 SINNIAH SK, 1996, J AM CHEM SOC, V118, P8925 SMITH RK, 2004, PROG SURF SCI, V75, P1 SPINKE J, 1993, J CHEM PHYS, V99, P7012 STAMOU D, 2003, ANGEW CHEM INT EDIT, V42, P5580 STANISH I, 2001, J AM CHEM SOC, V123, P1008 STEVENS F, 1999, LANGMUIR, V15, P207 STOECKLI M, 1999, J AM SOC MASS SPECTR, V10, P67 STORRI S, 1998, BIOSENS BIOELECTRON, V13, P347 SU XD, 2005, LANGMUIR, V21, P348 SULLIVAN TP, 2003, EUR J ORG CHEM JAN, P17 SVEDHEM S, 2003, CHEMBIOCHEM, V4, P339 TANNENBAUM R, 2002, LANGMUIR, V18, P5592 TARLOV MJ, 1993, J AM CHEM SOC, V115, P5305 TOLLNER K, 1997, SCIENCE, V278, P2100 TOOMEY R, 2004, MACROMOLECULES, V37, P882 TURNER NH, 2000, ANAL CHEM, V72, R99 ULMAN A, 1991, INTRO ULTRATHIN ORGA ULMAN A, 1995, CHARACTERIZATION ORG ULMAN A, 1996, CHEM REV, V96, P1533 VANCSO GJ, 1998, ACS SYM SER, V694, P67 VANCSO GJ, 1999, MICROSTRUCTURE MICTR, V741, P317 VANCSO GJ, 2005, ADV POLYM SCI, V182, P55 VANDERWERF KO, 1994, APPL PHYS LETT, V65, P1195 VANOUDENAARDEN A, 1999, SCIENCE, V285, P1046 VANRYSWYK H, 1996, LANGMUIR, V12, P6143 WAGNER P, 1994, FEBS LETT, V356, P267 WAGNER P, 1996, BIOPHYS J, V70, P135 WANG J, 1992, ACS SYM SER, V487, P125 WANG JH, 1997, J AM CHEM SOC, V119, P12796 WATTS TH, 1984, P NATL ACAD SCI USA, V81, P7564 WATTS TH, 1986, NATURE, V320, P179 WESSA T, 1998, FRESEN J ANAL CHEM, V361, P239 WILBUR JL, 1994, ADV MATER, V6, P600 WILBUR JL, 1999, NANOTECHNOLOGY, P339 WIRTH MJ, 1999, CHEM REV, V99, P2843 WOJTYK JTC, 2002, LANGMUIR, V18, P6081 WOUTERS D, 2004, ANGEW CHEM INT EDIT, V43, P2480 XIA YN, 1998, ANNU REV MATER SCI, V28, P153 YAN L, 2004, J MACROMOL SCI-POL C, V44, P175 YANG ZP, 2000, LANGMUIR, V16, P7482 YOSHINAISHII C, 2003, J AM CHEM SOC, V125, P3696 ZHANG ZH, 2003, MACROMOLECULES, V36, P7689 ZHOU XC, 2004, LANGMUIR, V20, P8877 ZHU H, 2002, CURR OPIN CELL BIOL, V14, P173 Review HEIDELBERGER PLATZ 3, D-14197 BERLIN, GERMANYISI:000239275000007:Univ Twente, MESA Inst Nanotechnol, NL-7500 AE Enschede, Netherlands. Univ Twente, Fac Sci & Technol, Dept Mat Sci & Technol Polymers, NL-7500 AE Enschede, Netherlands. Schonherr, H, Univ Twente, MESA Inst Nanotechnol, POB 217, NL-7500 AE Enschede, Netherlands. h.schonherr@tnw.utwente.nl g.j.vancso@tnw.utwente.nlinternal-pdf://2006_Adv Poly Sci_ Organic and macromolec-2883543055/2006_Adv Poly Sci_ Organic and macromolecular films and assemblies as (bio)reactive platforms.pdf MXlbl.govinternal-pdf://2006 JPC Sacha Induced Water Condensation and Brige  ~?BFarkas, N. Ehrman, J. D. Evans, E. A. Ramsier, R. D. Dagata, J. A.20068High-voltage parallel writing on iron nitride thin films 1340-1343(Journal of Vacuum Science & Technology A244LOCAL OXIDATION NANOLITHOGRAPHY; ATOMIC-FORCE MICROSCOPE; DIP-PEN NANOLITHOGRAPHY; MAGNETIC NANOSTRUCTURES; NANO-OXIDATION; METAL-FILMS; LITHOGRAPHY; GROWTH; ZIRCONIUM; SILICONArticleJul-AugWe report large area patterning of sputter-deposited FeN thin films by a high-voltage parallel writing technique that was recently developed to modify ZrN surfaces. Systematically patterned 15-100-nm-thick FeN films consisting of features with well-defined sizes and shapes are obtained by applying high dc voltages between a stamp and the samples. During the process the oxide dissolves, exposing the substrate beneath. This controlled breakdown eliminates the need for any postexposure etching. The single-step imprinting method presented here provides an emerging route to fabricate isolated FeN geometrical structures on silicon substrates for magnetic applications. (c) 2006 American Vacuum Society.://000239048100080 DTimes Cited: 0 Cited References: BAL M, 2002, APPL PHYS LETT, V81, P3479 BASELT DR, 1998, BIOSENS BIOELECTRON, V13, P731 CAVALLINI M, 2003, APPL PHYS LETT, V83, P5286 CHIEN FSS, 2001, J APPL PHYS, V89, P2465 DAGATA JA, UNPUB DREYER M, 2002, J APPL PHYS 3, V91, P8138 FARKAS N, 2003, J VAC SCI TECHNOL A, V21, P1188 FARKAS N, 2004, APPL PHYS LETT, V85, P5691 FARKAS N, 2004, J VAC SCI TECHNOL A, V22, P1879 FARKAS N, 2004, THIN SOLID FILMS, V447, P468 FEHLNER FP, 1970, OXID MET, V2, P59 FU L, 2003, NANO LETT, V3, P757 GALLAGHER WJ, 1997, J APPL PHYS 2A, V81, P3741 GUNDIAH G, 2004, APPL PHYS LETT, V84, P5341 GWO S, 1999, APPL PHYS LETT, V74, P1090 GWO S, 2001, J PHYS CHEM SOLIDS, V62, P1673 HELD R, 1998, PHYSICA E, V2, P748 HINDS KA, 2003, BLOOD, V102, P867 HIROOKA M, 2004, APPL PHYS LETT, V85, P1811 LEIBBRANDT GWR, 1992, PHYS REV LETT, V68, P1947 MELINTE S, 1998, SUPERLATTICE MICROST, V24, P79 NIU C, 2001, J VAC SCI TECHNOL 2, V19, P1947 QIN F, 2003, THIN SOLID FILMS, V444, P179 SHAPIRO EM, 2004, P NATL ACAD SCI USA, V101, P10901 TAKEMURA Y, 2005, ADV ENG MATER, V7, P170 TELLO M, 2003, APPL PHYS LETT, V83, P2339 TERRIS BD, 2000, J APPL PHYS 3, V87, P7004 WEEKES SM, 2005, J APPL PHYS, V97 WOOD DK, 2005, SENSOR ACTUAT A-PHYS, V120, P1 YANG XM, 2003, J VAC SCI TECHNOL B, V21, P3017 YOKOO A, 2003, J VAC SCI TECHNOL B, V21, P2966 YOSHIOKA H, 2000, MAGN RESON IMAGING, V18, P1079 ZHANG ZL, 2004, MAGN RESON MATER PHY, V17, P201ISI:000239048100080Univ Akron, Dept Phys, Akron, OH 44325 USA. Univ Akron, Dept Chem, Akron, OH 44325 USA. Univ Akron, Dept Chem Engn, Akron, OH 44325 USA. Natl Inst Stand & Technol, Div Precis Engn, Gaithersburg, MD 20899 USA. Ramsier, RD, Univ Akron, Dept Phys, Akron, OH 44325 USA. rex@uakron.eduinternal-pdf://2006 Journal of VacScie&TechA Farkas High-voltage parallel-1796539408/2006 Journal of VacScie&TechA Farkas High-voltage parallel.pdf 2v~?'Sacha, G. M. Verdaguer, A. Salmeron, M.2006]Induced water condensation and bridge formation by electric fields in atomic force microscopy 14870-14873Journal of Physical Chemistry B11030JDIP-PEN NANOLITHOGRAPHY; CAPILLARY CONDENSATION; PROBE; OXIDATION; SILICONArticleAugRWe present an analytical model that explains how, in humid environments, the electric field near a sharp tip enhances the formation of water menisci and bridges between the tip and a sample. The predictions of the model are compared with experimental measurements of the critical distance where the field strength causes bridge formation.://000239309500048 Times Cited: 0 Cited References: BATENI A, 2004, LANGMUIR, V20, P7589 BLUHM H, 1998, REV SCI INSTRUM, V69, P1781 CAPELLA B, 1999, SURF SCI REP, V34, P1 DAGATA JA, 2004, J APPL PHYS, V96, P2393 DELAZZER A, 1999, LANGMUIR, V15, P4551 GAO C, 1997, APPL PHYS LETT, V71, P1801 GARCIA R, 1999, J APPL PHYS, V86, P1898 GOMEZMONIVAS S, 2000, APPL PHYS LETT, V76, P2955 GOMEZMONIVAS S, 2001, APPL PHYS LETT, V79, P4048 GOMEZMONIVAS S, 2003, PHYS REV LETT, V91, P56101 ISRAELACHVILI JN, 1991, INTERMOLECULAR SURFA JACKSON JD, 1975, CLASSICAL ELECTRODYN JANG JY, 2004, PHYS REV LETT, V92 KOHONEN MM, 1999, PHYS REV LETT, V82, P4667 LEE KB, 2002, SCIENCE, V295, P1702 MORIMOTO K, 1997, APPL SURF SCI, V117, P652 PARAMONOV PB, 2005, J CHEM PHYS, V123 PINER RD, 1999, SCIENCE, V283, P661 RESTAGNO F, 2000, PHYS REV LETT, V84, P2433 SACHA GM, 2005, APPL PHYS LETT, V86, P23101 SADER JE, 1999, REV SCI INSTRUM, V70, P3967 STIFTER T, 2000, PHYS REV B, V62, P13667 SZOSZKIEWICZ R, 2005, APPL PHYS LETT, V87 THUNDAT T, 1993, SURF SCI LETT, V294, P939 VALENCIA A, 2001, LANGMUIR, V17, P3390 VERDAGUER A, 2005, J CHEM PHYS, V123 VERDAGUER A, 2006, CHEM REV, V106, P1478ISI:000239309500048Univ Calif Berkeley, Div Mat Sci, Lawrence Berkeley Natl Lab, Berkeley, CA 94720 USA. Sacha, GM, Univ Calif Berkeley, Div Mat Sci, Lawrence Berkeley Natl Lab, Berkeley, CA 94720 USA. sgomezmonivas@ ~?LIm, J. Lee, M. Myung, S. Huang, L. Rao, S. G. Lee, D. J. Koh, J. Hong, S. H.2006Directed-assembly of single-walled carbon nanotubes using self-assembled monolayer patterns comprising conjugated molecular wires 3569-3573Nanotechnology1714NDIP-PEN NANOLITHOGRAPHY; DEPOSITION; TEMPLATES; SURFACE; TRANSISTORS; FEATURESArticleJul@Self-assembled monolayer (SAM) patterns on electrodes are often utilized to guide the assembly of single-walled carbon nanotubes (SWCNTs) onto the electrodes to form desired device structures. In this case, the SWCNTs are in contact with the electrodes through the SAM which comprises molecular wires. Presumably, it is desirable to use conjugated molecular wires for a low contact resistance because they have been reported as a better electric conductor than non-conjugated ones. However, until now, the directed-assembly of SWCNTs has been driven mostly via molecular wires with alkane backbones which are known to be relatively poor conductors. Herein, we report large-scale directed-assembly of SWCNTs utilizing SAM patterns comprising conjugated molecular wires. We achieved highly selective adsorption and precision alignment of SWCNTs utilizing polar SAM patterns comprising conjugated molecular wires, while SAM patterns with non-polar terminal groups efficiently prevented adsorption of SWCNTs. Furthermore, we developed a process for assembling a SWCNT across two electrodes coated with conjugated molecular wires, and the electrical conduction through the SWCNT was measured via a conducting atomic force microscope. This result could be an important guideline for large-scale directed-assembly of SWCNT-based devices in the future.://000238969700036 Times Cited: 0 Cited References: BACHTOLD A, 2001, SCIENCE, V294, P1317 BAUGHMAN RH, 1999, SCIENCE, V284, P1340 BEEBE JM, 2002, J AM CHEM SOC, V124, P11268 CHO N, 2006, J CHEM PHYS, V124 DAI HJ, 1996, NATURE, V384, P147 DEHEER WA, 1995, SCIENCE, V270, P1179 FAN SS, 1999, SCIENCE, V283, P512 FRANK S, 1998, SCIENCE, V280, P1744 HONG S, 2000, SUPERLATTICE MICROST, V28, P289 HUANG Y, 2001, SCIENCE, V291, P630 JASCHKE M, 1995, LANGMUIR, V11, P1061 KONG J, 1998, NATURE, V395, P878 KRUPKE R, 2003, SCIENCE, V301, P344 LIU J, 1998, SCIENCE, V280, P1253 LIU J, 1999, CHEM PHYS LETT, V303, P125 MAHAPATRO AK, 2006, APPL PHYS LETT, V88 MANANDHAR P, 2003, PHYS REV LETT, V90 MARTEL R, 1998, APPL PHYS LETT, V73, P2447 MCLEAN RS, 2006, NANO LETT, V6, P55 MYUNG S, 2005, ADV MATER, V17, P2361 NYAMJAV D, 2003, ADV MATER, V15, P1805 PINER RD, 1999, SCIENCE, V283, P661 RAO SG, 2003, NATURE, V425, P36 RUECKES T, 2000, SCIENCE, V289, P94 SAMANTA MP, 1996, PHYS REV B, V53, P7626 SHEEHAN PE, 2002, PHYS REV LETT, V88 WANG YH, 2006, P NATL ACAD SCI USA, V103, P2026 WILBUR JL, 1995, LANGMUIR, V11, P825 XIA YN, 1995, J AM CHEM SOC, V117, P3274ISI:0002389697000363Seoul Natl Univ, Sch Phys, Seoul 151747, South Korea. Seoul Natl Univ, NANO Syst Inst, Seoul 151747, South Korea. Northwestern Univ, Dept Chem, Evanston, IL 60208 USA. Florida State Univ, Dept Phys, Tallahassee, FL 32306 USA. Im, J, Seoul Natl Univ, Sch Phys, Seoul 151747, South Korea. shong@phya.snu.ac.krinternal-pdf://2006 Nanotechnology Im Directed-assembly of single-walled ca-1830201104/2006 Nanotechnology Im Directed-assembly of single-walled carbon nanotubes.pdf their analogs.pdf0-walled carbon nanotubes.pdf8~??Rohde, R. D. Agnew, H. D. Yeo, W. S. Bailey, R. C. Heath, J. R.2006XA non-oxidative approach toward chemically and electrochemically functionalizing Si(111) 9518-9525(Journal of the American Chemical Society12829SELF-ASSEMBLED MONOLAYERS; DIP-PEN NANOLITHOGRAPHY; HYDROGEN-TERMINATED SILICON(111); SELECTIVE FUNCTIONALIZATION; RECOMBINATION VELOCITY; CRYSTALLINE SI(111); ELECTRODE SURFACES; ALKYL MONOLAYERS; CLICK CHEMISTRY; PROTEINArticleJulA general method for the non-oxidative functionalization of single-crystal silicon(111) surfaces is described. The silicon surface is fully acetylenylated using two-step chlorination/alkylation chemistry. A benzoquinone-masked primary amine is attached to this surface via Cu(I)-catalyzed Huisgen 1,3-dipolar cycloaddition ("click" chemistry). The benzoquinone is electrochemically reduced, resulting in quantitative cleavage of the molecule and exposing the amine terminus. Molecules presenting a carboxylic acid have been immobilized to the exposed amine sites. X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FTIR), cyclic voltammetry (CV), and contact angle goniometry were utilized to characterize and quantitate each step in the functionalization process. This work represents a strategy for providing a general platform that can incorporate organic and biological molecules on Si(111) with minimal oxidation of the silicon surface.://000239120700067  Times Cited: 0 Cited References: BABICSAMARDZIJA K, 2005, LANGMUIR, V21, P12187 BANSAL A, 1998, J PHYS CHEM B, V102, P4058 BANSAL A, 2001, J PHYS CHEM B, V105, P10266 BECKMANN N, 2005, P NATL ACAD SCI USA, V102, P14587 BOCK VD, 2006, EUR J ORG CHEM, P51 BOUKHERROUB R, 1999, J AM CHEM SOC, V121, P11513 BUNIMOVICH YL, 2004, LANGMUIR, V20, P10630 BURIAK JM, 1998, J AM CHEM SOC, V120, P1339 CHIDSEY CED, 1990, J AM CHEM SOC, V112, P4301 CICERO RL, 2000, LANGMUIR, V16, P5688 COLLMAN JP, 2004, LANGMUIR, V20, P1051 COLLMAN JP, 2006, LANGMUIR, V22, P2457 CRAIGHEAD HG, 2001, CURR OPIN SOLID ST M, V5, P177 CURRELI M, 2005, J AM CHEM SOC, V127, P6922 DEVARAJ NK, 2005, J AM CHEM SOC, V127, P8600 DEVARAJ NK, 2006, J AM CHEM SOC, V128, P1794 DUMAS P, 1990, PHYS REV LETT, V65, P1124 EFFENBERGER F, 1998, ANGEW CHEM INT EDIT, V37, P2462 FAN R, 2005, NANO LETT, V5, P1633 GIOVANELLI D, 2003, ANAL LETT, V36, P2941 HABER JA, 2002, J PHYS CHEM B, V106, P3639 HODNELAND CD, 2000, J AM CHEM SOC, V122, P4235 HU K, 1997, J PHYS CHEM B, V101, P8298 HURLEY PT, UNPUB ISRAELACHVILI J, 1985, INTERMOLECULAR SURFA JUNG DR, 2001, CRIT REV BIOTECHNOL, V21, P111 JUNG H, 2004, NANO LETT, V4, P2171 KARNIK R, 2005, NANO LETT, V5, P1638 KOLB HC, 2001, ANGEW CHEM INT EDIT, V40, P2004 LEE JK, 2004, LANGMUIR, V20, P3844 LEE KB, 2002, SCIENCE, V295, P1702 LI HM, 2005, J AM CHEM SOC, V127, P14518 LINFORD MR, 1995, J AM CHEM SOC, V117, P3145 LUMMERSTORFER T, 2004, J PHYS CHEM B, V108, P3963 NEMANICK EJ, 2005, THESIS CALTECH NEMANICK EJ, 2006, IN PRESS J PHYS CH B PINER RD, 1999, SCIENCE, V283, P661 RECCIUS CH, 2005, PHYS REV LETT, V95 ROUSSEL C, 2003, CHEMPHYSCHEM, V4, P200 ROYEA WJ, 2000, APPL PHYS LETT, V77, P1988 SIEVAL AB, 1998, LANGMUIR, V14, P1759 SOLARES SD, 2006, J AM CHEM SOC, V128, P3850 STAVIS SM, 2005, J APPL PHYS, V98 STEWART MP, 2001, J AM CHEM SOC, V123, P7821 STRONG L, 1988, LANGMUIR, V4, P546 SUNG MM, 1997, LANGMUIR, V13, P6164 WEBB LJ, 2003, J PHYS CHEM B, V107, P5404 WEBB LJ, 2005, J CHEM PHYS B, V9, P3930 WEBB LJ, 2006, J PHYS CHEM B, V110, P7349 YABLONOVITCH E, 1986, PHYS REV LETT, V57, P249 YEO WS, 2001, CHEM BIOCH, P590 YEO WS, 2003, J AM CHEM SOC, V125, P14994 YEO WS, 2004, ADV MATER, V16, P1352 YOUSAF MN, 1999, J AM CHEM SOC, V121, P4286 YU H, 2006, IN PRESS APPL PHYS L YU HB, 2005, J PHYS CHEM B, V109, P671 YUE M, 2004, J MICROELECTROMECH S, V13, P290 ZHANG Y, 2006, ANAL CHEM, V78, P2001 ZHENG A, 1999, J ORG CHEM, V64, P156 ZHENG GF, 2005, NAT BIOTECHNOL, V23, P1294 ZIRBS R, 2005, LANGMUIR, V21, P8414ISI:000239120700067CALTECH, Div Chem & Chem Engn, Pasadena, CA 91125 USA. Heath, JR, CALTECH, Div Chem & Chem Engn, MC 127-72, Pasadena, CA 91125 USA. heath@caltech.eduinternal-pdf://2006 JACS Rohde Non-Oxidative functionalization of single cyr-3558318608/2006 JACS Rohde Non-Oxidative functionalization of single cyrstal silicon.pdf ITd their analogs-0588899600/2006 CurrentNanoSci Briones Nucleic acids and  ~?8Johannes, M. S. Kuniholm, J. F. Cole, D. G. Clark, R. L.2006NAutomated CAD/CAM-based nanolithography using a custom atomic force microscope236-2397IEEE Transactions on Automation Science and Engineering33atomic force microscopy (AFM); computer-aided design/computer-aided manufacturing (CAD/CAM); lithography; nanotechnology; oxidation DIP-PEN NANOLITHOGRAPHY; SILICON; OXIDATION; AFMArticleJul We report the development of a novel nanolithographic system that combines the design capabilities of computer-aided design/computer-aided manufacturing (CAD/CAM) software with the nanolithographic abilities of the atomic force microscope (AFM). The AFM is a powerful tool for research at the nanoscale and can be used to perform a variety of serial nanolithographic techniques. A custom-built three-axis AFM system, designed to execute nanolithography, has been constructed and interfaced with a CAD/CAM design environment. This technique utilizes the CAD/CAM software to create, in a virtual design environment, the desired nanoscale patterns. Then, using a G-code interpreter and software algorithms to control the three-dimensional motion of the system, the design is replicated automatically by using conventional nanolithographic procedures. In this report, AFM-based anodization lithography on a silicon wafer and subsequent AFM imaging is used to confirm the successful automatic replication of the desired nanoscale patterns.://000239032600006 Times Cited: 0 Cited References: 2004, ACE CONVERTER PROGRA BINNIG G, 1986, ATOMIC FORCE MICROSC, P930 BUSTAMANTE C, 2003, NATURE, V421, P423 DAGATA JA, 1990, APPL PHYS LETT, V56, P2001 DAY HC, 1993, APPL PHYS LETT, V62, P2691 FOTIADIS D, 2002, MICRON, V33, P385 GINGER DS, 2004, ANGEW CHEM INT EDIT, V43, P30 GORDON AE, 1995, J VAC SCI TECHNOL B, V13, P2805 HAFNER JH, 2001, PROG BIOPHYS MOL BIO, V77, P73 JASCHKE M, 1995, LANGMUIR, V11, P1061 PINER RD, 1999, SCIENCE, V283, P661 QUATE CF, 1997, SURF SCI, V386, P259 TELLO M, 2003, APPL PHYS LETT, V83, P2339 WILBUR JL, 1995, ADV MATER, V7, P649 XU S, 1997, LANGMUIR, V13, P127ISI:000239032600006Duke Univ, Dept Mech Engn & Mat Sci, Durham, NC 27708 USA. Johannes, MS, Duke Univ, Dept Mech Engn & Mat Sci, Durham, NC 27708 USA. rclark@duke.eduinternal-pdf://2006 IEEE Johannes Automated CAD-CAM-based Nanolith.-2098809872/2006 IEEE Johannes Automated CAD-CAM-based Nanolith..pdf Ecsic.esinternal-pdf://2006 CurrentNanoSci Briones Nucleic acids an*f)4~?Briones, C. Martin-Gago, J. A.2006JNucleic acids and their analogs as nanomaterials for biosensor development257-273Current Nanoscience23SELF-ASSEMBLED MONOLAYERS; SINGLE-NUCLEOTIDE POLYMORPHISMS; DENSITY OLIGONUCLEOTIDE ARRAYS; DIP-PEN NANOLITHOGRAPHY; ATOMIC-FORCE MICROSCOPY; DNA MICROARRAYS; ELECTROCHEMICAL DETECTION; MASS-SPECTROMETRY; GENE-EXPRESSION; GOLD SURFACESReviewAugNucleic acids are natural biopolymers that store the genetic information of organisms. This makes the detection and characterization of DNA and RNA a relevant task in biotechnology, with applications ranging from medicine to environmental control. During the last decades, a large effort has been focused on the development of biosensors, among them those devoted to the detection of nucleic acids in natural samples and those that include nucleic acids as nanosized capture probes for different biomolecules. DNA microarray technology has been successfully used in biotechnological applications including genotyping and gene expression studies. Nevertheless, the performance of DNA microarrays has a limitation imposed by the need of a previous fluorescent labeling of the target molecule to be analyzed. This encouraged the use of alternative detection methods, such as optical and electrochemical ones, and recently others based on surface characterization techniques. New trends in nanotechnology point towards new tools for manipulating molecules and macromolecules that could be developed as high performance biosensors. This interdisciplinary approach towards the integration of novel biosensors can benefit from the capability of certain polymers to form self-assembled monolayers (SAMs) on different surfaces. Thiol-modified DNA can form SAMs on gold surfaces with reduced efficiency, and the biological activity of the probe is decreased upon adsorption. Therefore, thiolated DNA has a very limited use in biosensor development. These constraints have been successfully by-passed using uncharged, artificial analogs of natural nucleic acids, such as peptide nucleic acids (PNAs), as molecular probes. This contribution reviews the state of the art in the use of nucleic acids and their analogs as biosensor nanomaterials, and summarizes the novel approach towards the development of biosensors based on SAMs of PNAs. 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CSIC, INTA, Ctr Astrobiol, Madrid 28850, Spain. Martin-Gago, JA, CSIC, Inst Ciencia Mat Madrid, Madrid 28049, Spain. gago@icmm.~?Hanumanthu, R. Stebe, K. J.2006YEquilibrium shapes and locations of axisymmetric, liquid drops on conical, solid surfaces227-239?Colloids and Surfaces A-Physicochemical and Engineering Aspects282 dip-pen nanolithography; axisymmetric interface; wettability; wetting gradient; contact angle; surface tension; line tension DIP-PEN NANOLITHOGRAPHY; LINE TENSION; CONTACT ANGLES; INTERFACIAL-TENSION; SIZE DEPENDENCE; SYSTEMS; WETTABILITY; PARTICLES; CYLINDERS; SESSILEArticleJul0Micro- and nano-scale liquid droplets must be precisely placed in proximity to conical solid tips in applications that include AFM tip dip-pen nanolithography. This seemingly simple task is strongly dependent on wetting conditions of the drop on the tip surface. Over a wide range of wetting conditions and drop Volumes, drops can situate far from a conical needle apex at equilibrium, which can hinder the effectiveness of the respective applications. Needle geometry also affects drop location. On a right conical needle, liquid drops that wet the needle surface locate away from the apex. However, by careful consideration of their geometry, needles can be engineered to retain liquid drops near the tip or some other region of interest. In this work, a theoretical model is developed that predicts axisymmetric, equilibrium drop locations and shapes on conical, solid surfaces as a function of drop volume, needle geometry/shape, needle surface wettability (contact angle), liquid surface tension, line tension, and gravity. (c) 2006 Elsevier B.V. All rights reserved.://000238730200025 Times Cited: 0 Cited References: AMIRFAZLI A, 2000, LANGMUIR, V16, P2024 AMIRFAZLI A, 2003, J COLLOID INTERF SCI, V265, P152 AVEYARD R, 1996, J CHEM SOC FARADAY T, V92, P4271 AVEYARD R, 1996, J CHEM SOC FARADAY T, V92, P85 BABU SR, 1987, J COLLOID INTERF SCI, V116, P350 BAUER C, 2000, PHYS REV E B, V62, P2428 CARROLL BJ, 1986, LANGMUIR, V2, P248 DEGENNES PG, 2004, CAPILLARITY WETTING DUNCAN D, 1995, J COLLOID INTERF SCI, V169, P256 GAYDOS J, 1987, J COLLOID INTERF SCI, V120, P76 GETTA T, 1998, PHYS REV E, V57, P655 GINGER DS, 2004, ANGEW CHEM INT EDIT, V43, P31 GU YG, 1996, J COLLOID INTERF SCI, V180, P212 HARTLAND S, 1976, AXI SYMMETRIC FLUID HONG MH, 2000, APPL PHYS LETT, V77, P2604 HOORFAR M, 2005, ADV COLLOID INTERFAC, V114, P103 HUH C, 1983, J COLLOID INTERF SCI, V91, P472 JANG J, 2003, PHYS REV LETT, V90 JANG JK, 2004, J CHEM PHYS, V120, P1157 JANG JY, 2001, J CHEM PHYS, V115, P2721 JANG JY, 2002, J CHEM PHYS, V116, P3875 KREYSZIG E, 1999, ADV ENG MATH LEWIS A, 1999, APPL PHYS LETT, V75, P2689 LUCASSEN J, 1992, LANGMUIR, V8, P3093 MCHALE G, 1997, J COLLOID INTERF SCI, V186, P453 MCHALE G, 2001, OIL GAS SCI TECHNOL, V56, P47 MIRKIN CA, 2001, CHEMPHYSCHEM, V2, P37 MUGELE F, 2005, J PHYS-CONDENS MAT, V17, R705 NAM JM, 2004, ANGEW CHEM INT EDIT, V43, P1246 PINER RD, 1999, SCIENCE, V283, P661 PLATIKANOV D, 1980, J COLLOID INTERF SCI, V75, P612 QU WL, 1998, COLLOID SURFACE A, V144, P275 ROTENBERG Y, 1983, J COLLOID INTERF SCI, V93, P169 SCHELUDKO A, 1976, J CHEM SOC F1, V72, P2815 SIFTER T, 2000, PHYS REV B, V62, P13667 SU M, 2004, APPL PHYS LETT, V84, P4200 TAKATA Y, 2005, LANGMUIR, V21, P8594 TARAZONA P, 1981, J CHEM PHYS, V75, P3114 TOSHEV BV, 1988, LANGMUIR, V4, P489 WIDOM B, 1995, J PHYS CHEM-US, V99, P2803 ZHANG H, 2004, CHEM MATER, V16, P1480ISI:000238730200025Johns Hopkins Univ, Dept Chem & Biomol Engn, Baltimore, MD 21218 USA. Stebe, KJ, Johns Hopkins Univ, Dept Chem & Biomol Engn, 221 Maryland Hall,3400 N Charles St, Baltimore, MD 21218 USA. rhanuma1@jhem.jhu.edu kjs@jhu.eduinternal-pdf://2006 Colloids & Surfaces Hanumanthu Equilibrium Shapes & Locations-2048577040/2006 Colloids & Surfaces Hanumanthu Equilibrium Shapes & Locations.pdfPxids & Surfaces Hanumanthu Equilibrium Shapes & Locations.pdf  ~?(Li, J. Wang, Y. J. Lu, Z. H. Chan, M. S.2006Enhancing deoxyribonucleic acid (DNA) detection sensitivity through microconcentration on patterned fluorocarbon polymer surface34-39Analytica Chimica Acta5711deoxyribonucleic acid (DNA) detection; sensitivity; microconcentration; patterning; hydrophobic surface DIP-PEN NANOLITHOGRAPHY; HYBRIDIZATION KINETICS; OLIGONUCLEOTIDES; LITHOGRAPHY; MICROARRAYS; NANOARRAYS; CAPILLARY; BIOCHIPS; ADHESION; PLASMAArticleJun/A microconcentration concept is proposed to enhance the sensitivity of deoxyribonucleic acid (DNA) hybridization due to evaporation of the hybridization solution on a patterned hydrophobic fluorocarbon polymer (FCP) surface. The combination of microconcentration and hybridization processes provides a tool to manipulate nanoliter solution. To fabricate a patterned DNA microarray with hydrophobic surrounding surface, a plasma polymerization and lift-off protocol was designed so that the process can be carried out in a standard microelectronic fabrication laboratory with minimal adjustments on the equipment. After microconcentration, a 1 mu L hybridization solution can be concentrated to below 10 nL, which improves the hybridization sensitivity by a factor of 100. (c) 2006 Elsevier B.V. All rights reserved.://000238720100006 Times Cited: 0 Cited References: ANDERSSON H, 2001, SENSOR ACTUAT B-CHEM, V75, P136 CHAN V, 1995, BIOPHYS J, V69, P2243 CHEEK BJ, 2001, ANAL CHEM, V73, P5777 CHRISEY LA, 1996, NUCLEIC ACIDS RES, V24, P3040 DEEGAN RD, 1997, NATURE, V389, P827 DEEGAN RD, 2000, PHYS REV E, V61, P475 DEMERS LM, 2002, SCIENCE, V296, P1836 ERICKSON D, 2003, ANAL BIOCHEM, V317, P186 HALPERIN A, 2005, BIOPHYS J, V89, P796 IVANOVA EP, 2002, LANGMUIR, V18, P9539 KANE RS, 1999, BIOMATERIALS, V20, P2363 KOHARA Y, 2002, NUCLEIC ACIDS RES, V30 LEE KB, 2002, SCIENCE, V295, P1702 LEE KB, 2004, NANO LETT, V4, P1869 LEE SH, 2004, SENSOR ACTUAT B-CHEM, V99, P623 LENIGK R, 2001, LANGMUIR, V17, P2497 LIVACHE T, 2003, J PHARMACEUT BIOMED, V32, P687 MAKOHLISO SA, 1998, BIOSENS BIOELECTRON, V13, P1227 MARRIAN CRK, 1996, MICROELECTRON ENG, V32, P173 MATSUMOTO Y, 1998, SENSOR ACTUAT A-PHYS, V66, P308 MULLER U, 2003, J ASS LAB AUTOM, V8, P96 PAPPAERT K, 2003, CHEM ENG SCI, V58, P4921 ROGERS YH, 1999, ANAL BIOCHEM, V266, P23 RUARDIJ TG, 2000, IEEE T BIO-MED ENG, V47, P1593 TOEGL A, 2003, J BIOMOL TECH, V14, P197 WANG Y, 2003, ANAL CHEM, V75, P1130 ZHANG YC, 2003, ANAL CHEM, V75, P3267ISI:000238720100006Hong Kong Univ Sci & Technol, Dept Elect & Elect Engn, Kowloon, Hong Kong, Peoples R China. SE Univ, Minist Educ, Key Lab Mol & Biomol Elect, Nanjing 210096, Peoples R China. Li, J, Hong Kong Univ Sci & Technol, Dept Elect & Elect Engn, Kowloon, Hong Kong, Peoples R China. eelij@ust.hkinternal-pdf://2006 AnaChimActa Li Enhancing DNA detection sensitivity-0035390224/2006 AnaChimActa Li Enhancing DNA detection sensitivity.pdfT00\2006 AnaChimActa Li Enhancing DNA detection sensitivity.pdf ~?(Im, J. Kang, J. Lee, M. Kim, B. Hong, S.2006uSelective adsorption and alignment behaviors of double- and multiwalled carbon nanotubes on bare Au and SiO2 surfaces 12839-12